RT info:eu-repo/semantics/article T1 Microcellular polymer films based on cross-linked 1-vinyl-2-pyrrolidone and methyl methacrylate A1 Reglero Ruiz, José Antonio A1 Vallejos Calzada, Saúl A1 Pascual Portal, Blanca Sol A1 Ramos Rodríguez, Cipriano A1 Beltrán Calvo, Sagrario A1 García García, Félix Clemente A1 García Pérez, José Miguel K1 Microcellular polymer foam K1 Films K1 Cross-linking K1 Tensile properties K1 ScCO2 foaming K1 Química orgánica K1 Chemistry, Organic AB A series of cross-linked copolymer films based on 1-vinyl-2-pyrrolidone and methyl methacrylate were produced using different poly(ethylene glycol) dimethacrylates as cross-linking agents. The average molecular mass of the cross-linking agent was varied, then allowing the foaming process using supercritical CO2 (ScCO2), obtaining microcellular films with different cellular structures as a function of the molecular mass of the cross-linking agent. The chemical structure, swelling behavior, CO2 uptake and cellular morphology of the materials were studied. Finally, the influence of the different cross-linking agents in the mechanical properties was also evaluated by measuring the tensile properties of the microcellular films. PB Elsevier SN 0896-8446 YR 2018 FD 2018-10 LK http://hdl.handle.net/10259/4861 UL http://hdl.handle.net/10259/4861 LA eng NO Fondo Europeo de Desarrollo Regional (FEDER) and the Spanish Agencia Estatal de Investigación (AEI) (MAT2017-84501-R) DS Repositorio Institucional de la Universidad de Burgos RD 23-nov-2024