RT info:eu-repo/semantics/article
T1 Gold(I)-catalyzed diastereoselective synthesis of 1-α-oxybenzyl-1H-indenes
A1 Virumbrales Ortiz, Cintia
A1 Suarez Pantiga, Samuel
A1 Solas Luera, Marta
A1 Fernández Rodríguez, Manuel A.
A1 Sanz Díez, Roberto
K1 Química orgánica
K1 Chemistry, Organic
AB The gold(I)-catalyzed oxycyclization of β-aryl monosubstitutedo-(alkynyl)styrenes gives rise to 1-α-methoxy or 1-α-hydroxybenzyl-1H-indenes in a diastereospecific way. In contrast toβ,β-disubstituted o-(alkynyl)styrenes, the stereochemical outcomeof this process, diastereospecific reaction supports the higher contributionof a gold intermediate with a cyclopropylcarbene-likecharacter.
PB Royal Society of Chemistry
SN 1477-0520
YR 2018
FD 2018-04
LK http://hdl.handle.net/10259/4920
UL http://hdl.handle.net/10259/4920
LA eng
NO Ministerio de Economía yCompetitividad (MINECO) and FEDER (CTQ2016-75023-C2-1-P), and Junta de Castilla y León and FEDER (BU076U16)
DS Repositorio Institucional de la Universidad de Burgos
RD 20-abr-2024