RT info:eu-repo/semantics/article T1 Spectroelectrochemistry at free-standing carbon nanotubes electrodes A1 Ibáñez Martínez, David A1 Garoz Ruiz, Jesús A1 Plana, Daniela . A1 Heras Vidaurre, Aránzazu A1 Fermín, David J. . A1 Colina Santamaría, Álvaro K1 spectroelectrochemistry K1 nanotubes K1 nanoparticles K1 Química analítica K1 Chemistry, Analytic AB A versatile and low-cost methodology for fabricating free-standing carbon nanotubes (CNT) electrodes for electrochemical and spectroelectrochemical applications is described. The uniformity, flexibility and resistance to bending of these films make them one of the most interesting membranes in a wide range of applications. CNT electrodes were characterized by Raman spectroscopy and scanning electron microscopy and their electrochemical performance was assessed employing various redox species such as ferrocenemethanol, hexacyanoferrate (II) and dopamine. Free-standing single-walled CNT electrodes exhibit good conductivity and transparency to UV–vis radiation, making them suitable as optically transparent electrodes. This is exemplified by monitoring, using UV–vis absorption spectroelectrochemistry, the electrodeposition of gold nanoparticles (AuNPs) on one face of the free-standing CNT electrodes, while the other face remained unmodified PB Elsevier SN 1388-2481 YR 2016 FD 2016-11 LK http://hdl.handle.net/10259/4940 UL http://hdl.handle.net/10259/4940 LA eng NO Ministerio de Economía y Competitividad (CTQ2014-55583-R, CTQ2014-61914-EXP, CTQ2015-71955-REDT) and Junta de Castilla y León (BU033U16) DS Repositorio Institucional de la Universidad de Burgos RD 23-nov-2024