RT info:eu-repo/semantics/article T1 Determination of aluminium using different techniques based on the Al(III)-morin complex A1 Domínguez Renedo, Olga A1 Navarro Cuñado, A. Marta A1 Ventas Romay, Eduardo A1 Alonso Lomillo, Mª Asunción K1 Aluminium K1 Morin K1 Stripping voltammetry K1 UV–Vis spectroscopy K1 Fluorescence K1 Water samples K1 Química analítica K1 Chemistry, Analytic AB Three different methods for the determination of Al(III) in aqueous samples were compared. The different described procedures were based on the formation of the Al(III)-morin complex. UV–Vis spectrophotometry, spectrofluorimetry and differential pulse adsorptive stripping voltammetry (DPAdSV) techniques were compared under optimized experimental conditions. The DPAdSV method showed a better performance for the analysis of Al(III) in terms of capability of detection (70 nM) in comparison with the value obtained for UV–Vis spectrophotometric (300 nM) and spectrofluorimetic (110 nM) techniques. Thus, DPAdSV method was selected for the analysis of aluminium in river, tap and bottled water samples under the following optimized experimental conditions: pH = 4.4, deposition potential = +243 mV, deposition time = 210 s, giving satisfactory results. PB Elsevier SN 0039-9140 YR 2019 FD 2019-05 LK http://hdl.handle.net/10259/5332 UL http://hdl.handle.net/10259/5332 LA eng DS Repositorio Institucional de la Universidad de Burgos RD 22-dic-2024