RT info:eu-repo/semantics/article
T1 Selective synthesis of phenanthrenes and dihydrophenanthrenes via gold-catalyzed cycloisomerization of biphenyl embedded trienynes
A1 Milián, Ana
A1 García García, Patricia
A1 Pérez Redondo, Adrián
A1 Sanz Díez, Roberto
A1 Vaquero, Juan J.
A1 Fernández Rodríguez, Manuel A.
K1 Hydrocarbons
K1 Catalysts
K1 Isomerization
K1 Aromatic compounds
K1 Solvents
K1 Química orgánica
K1 Chemistry, Organic
AB Readily available o′-alkenyl-o-alkynylbiaryls, a particulartype of 1,7-enynes, undergo a selective cycloisomerization reaction inthe presence of a gold(I) catalyst to give interesting phenanthrene anddihydrophenanthrene derivatives in high yields. The solvent usedprovokes a switch in the evolution of the gold intermediate and plays akey role in the reaction outcome.
PB American Chemical Society
SN 1523-7060
YR 2020
FD 2020-11
LK http://hdl.handle.net/10259/5546
UL http://hdl.handle.net/10259/5546
LA eng
NO Ministerio de Economıá y Competitividad (MINECO), AEI and FEDER (projects CTQ2017- 85263-R and CTQ2016-75023-C2-1-P), Instituto de Salud Carlos III (FEDER funds, ISCIII RETIC REDINREN RD16/ 0009/0015), Junta de Castilla y León and FEDER (BU291P18), and University of Alcalá (projects CCGP2017- EXP/016 and CCG2018/EXP-008
DS Repositorio Institucional de la Universidad de Burgos
RD 21-nov-2024