RT info:eu-repo/semantics/article
T1 Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process
A1 Fernández-Fariña, Sandra
A1 González-Barcia, Luis M.
A1 Romero, María J.
A1 García Tojal, Javier
A1 Maneiro, Marcelino
A1 Seco, José M.
A1 Zaragoza, Guillermo
A1 Martínez-Calvo, Miguel
A1 González-Noya, Ana M.
A1 Pedrido Castiñeiras, Rosa
K1 Química inorgánica
K1 Chemistry, Inorganic
AB We present the first example of a silver double-tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate [Ag2(H2L)2]SO4. This is the first silver mediated desulfurization reaction.
PB Royal Society of Chemistry
YR 2022
FD 2022-02
LK http://hdl.handle.net/10259/6426
UL http://hdl.handle.net/10259/6426
LA eng
NO FEDER cofunded-grants: from Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia, 2017 GRC GI-1682 (ED431C 2017/01), 2018 GRC GI-1584 (ED431C 2018/13), MetalBIO Network (ED431D 2017/01), Ministerio de Ciencia, Innovación y Universidades, METALBIO (CTQ2017-90802-REDT) and MultiMetDrugs (RED2018-102471-T).
DS Repositorio Institucional de la Universidad de Burgos
RD 20-abr-2024