RT info:eu-repo/semantics/article
T1 Synthesis of a Tetracorannulene-perylenediimide That Acts as a Selective Receptor for C60 over C70
A1 García Calvo, Víctor
A1 Cuevas Vicario, José Vicente
A1 Barbero, Héctor
A1 Ferrero, Sergio
A1 Álvarez, Celedonio M.
A1 González, Jesús A.
A1 Díaz de Greñu Puertas, Borja
A1 García Calvo, José
A1 Torroba Pérez, Tomás
K1 Aromatic compounds
K1 Chemical structure
K1 Complexation
K1 Fluorescence
K1 Titration
K1 Química orgánica
K1 Chemistry, Organic
AB We report the use of a tetraborylated perylenediimide as starting material for the preparation of a tetracorannulene-perylenediimide that is able to bind up to two fullerene-C60 molecules by host–guest molecular recognition with preference over C70. Titration with fullerene-C60 is followed by a dramatic shift of the aromatic signals in 1H NMR and an initial increase in the fluorescence of the system. By this simple mechanism, fluorogenic sensing of fullerene-C60 is easily accomplished by an unprecedented fluorescent turn-on mechanism.
PB American Chemical Society
SN 1523-7060
YR 2019
FD 2019-08
LK http://hdl.handle.net/10259/6810
UL http://hdl.handle.net/10259/6810
LA eng
NO Ministerio de Economı́a y Competitividad, Spain (Projects CTQ2013-41067-P, CTQ2015-71353-R, and PGC2018-099470-B-100) and Junta de Castilla y León, Consejerı́a de Educación y Cultura y Fondo Social Europeo (Project BU263P18).
DS Repositorio Institucional de la Universidad de Burgos
RD 21-nov-2024