RT info:eu-repo/semantics/article
T1 Gold(I) Catalysis Applied to the Stereoselective Synthesis of Indeno[2,1-b]thiochromene Derivatives and Seleno Analogues
A1 Virumbrales Ortiz, Cintia
A1 Mahmoud Abd El Aleem Ali, Elremaily
A1 Suárez Pantiga, Samuel
A1 Fernández Rodríguez, Manuel A.
A1 Rodríguez, Félix
A1 Sanz Díez, Roberto
K1 Carbene compounds
K1 Gold
K1 Hydrocarbons
K1 Molecular structure
K1 Reaction products
K1 Química orgánica
K1 Chemistry, Organic
AB A gold(I)-catalyzed cascade reaction for the stereoselectivesynthesis of sulfur- or selenium-containing indeno[1,2-b]chromenederivatives from o-(alkynyl)styrenes substituted at the triple bond with athio- or seleno-aryl group is described. The reaction involves a doublecyclization process through a proposed key gold−cyclopropyl carbeneintermediate that evolves by the intramolecular addition of an aromatic tothe cyclopropane ring, affording polycyclic structures. The enantioselectiveversion was studied using gold(I) complexes bearing chiral ligands.
PB American Chemical Society
SN 1523-7060
YR 2022
FD 2022-10
LK http://hdl.handle.net/10259/7405
UL http://hdl.handle.net/10259/7405
LA eng
NO We gratefully acknowledge MICINN (PID2020-115789GBC21), “NextGenerationEU/PRTR” (PDC2021-120825-C21), Junta de Castilla y León, and FEDER (BU049P20) for financial support. The project leading to these results also received funding from the “la Caixa” Foundation, under Agreement LCF/PR/PR18/51130007 (CAIXA-UBU001). C.V. and S.S.-P. thank Junta de Castilla y León (Consejería de Educación) and Fondo Social Europeo for postdoctoral contracts.
DS Repositorio Institucional de la Universidad de Burgos
RD 04-dic-2024