RT info:eu-repo/semantics/article
T1 New fluorescent reporters capable of Ultra-sensitively detecting trinitrotoluene on surfaces: A proof-of-concept for finding hidden nitroaromatics in the workroom
A1 Revilla Cuesta, Andrea
A1 Abajo Cuadrado, Irene
A1 Medrano, María
A1 Martín Salgado, Mateo
A1 Pecori, Giuditta
A1 Rodríguez Rodríguez, Mª Teresa
A1 Hernando Muñoz, Carla
A1 García Calvo, José
A1 Arcos Martínez, Julia
A1 Torroba Pérez, Tomás
K1 2,4,6-Trinitrotoluene
K1 Improvised explosive devices
K1 Chemical sensors
K1 Fluorescent materials
K1 Chemical tests
K1 Swab alternatives
K1 Química orgánica
K1 Chemistry, Organic
AB We describe the proof of concept of a portable testing setup for the detection of trinitrotoluene (TNT), a common component in hidden explosive devices. The system allows for field-testing and generation of real-time results to test for TNT traces in surfaces by simply using a filter paper and a fluorescent reporter. In this way, the controlled trapping and detection of the analyte by a chemical sensor gives reliable results at extremely low concentrations of TNT on surfaces under real life conditions suitable for daily use in ordinary sampling for example at airlines luggage storage or sport locker rooms. The reported fluorescent methodology is very sensitive and selective, allowing for the trapping and detection of TNT by a fluorescent reporter to give reliable results at very low concentrations. As a complement, we report the preparation of a modified Sylgard film that is useful under real conditions for qualitative fluorescent detection of hidden traces of TNT on surfaces or fingers by a swab method. The combination of quantitative and qualitative detection of TNT traces on surfaces constitutes a comprehensive new method for the detection of hidden nitroaromatic explosives in the workplace.
PB Elsevier
SN 1010-6030
YR 2023
FD 2023-10
LK http://hdl.handle.net/10259/8221
UL http://hdl.handle.net/10259/8221
LA eng
NO This research was funded by the NATO Science for Peace and Security Programme (Grant SPS G5536) and the Ministerio de Ciencia e Innovación (Grants PID2019-111215RB-I00 and PDC2022-133955-I00). A. R. C. thanks Secretaría General de Universidades for a FPU18/03225 Grant.
DS Repositorio Institucional de la Universidad de Burgos
RD 21-nov-2024