RT info:eu-repo/semantics/article
T1 Microwave Dielectric Relaxation Spectroscopy Study of Alkan-1-ol/Alkylbenzoate Binary Solvents
A1 Navarro Cuñado, A. Marta
A1 García Ruiz, Begoña
A1 Ibeas Cortes, Saturnino
A1 Hoyuelos Álvaro, Fco. Javier
A1 Peñacoba Maestre, Indalecio A.
A1 Leal Villalba, José María
K1 Alcohols
K1 Ethanol
K1 Mixtures
K1 Organic compounds
K1 Solvents
K1 Química física
K1 Chemistry, Physical and theoretical
AB The structure and dynamics of alkan-1-ol/alkylbenzoate binary mixtures have been studied by microwave dielectric relaxation spectroscopy in the 200 MHz to 20 GHz frequency range. The binary mixtures of methanol, ethanol, propan-1-ol, butan-1-ol, and pentan-1-ol with methyl, ethyl, propyl, and butyl benzoates were studied at 298.15 K. The relaxational response of the pure alcohols, pure esters, and their binary mixtures over the full composition range is properly described by the Havriliak–Negami model. The alcohol content, alcohol length, and alkyl side-chain effects on the relaxational properties have been studied for these mixtures over the whole composition range. From the experimental readings, the effective and the corrective Kirkwood and Bruggeman correlation factors have been calculated. The data gathered have been interpreted in terms of the alkyl side-chain effect and their reliance on the mixture composition.
PB American Chemical Society
SN 1520-6106
YR 2013
FD 2013-10
LK http://hdl.handle.net/10259/8228
UL http://hdl.handle.net/10259/8228
LA eng
NO The financial support by Junta de Castilla y León, Fondo Social Europeo, Project BU-299A12-1 is gratefully acknowledged.
DS Repositorio Institucional de la Universidad de Burgos
RD 22-dic-2024