RT info:eu-repo/semantics/article
T1 Keto-Enol Tautomerism in Passerini and Ugi Adducts
A1 Pertejo Fernández, Pablo
A1 Sancho Medina, Andrea
A1 Hermosilla, Tomás
A1 González Saiz, Beatriz
A1 Gómez Ayuso, Javier
A1 Quesada Pato, Roberto
A1 Moreno Mediavilla, Daniel
A1 Carreira Barral, Israel
A1 García Valverde, María
K1 Keto-enol tautomerism
K1 Passerini adduct
K1 Ugi adduct
K1 Lactone
K1 Lactame
K1 2-hydroxyglutaric acid
K1 Química orgánica
K1 Chemistry, Organic
AB The use of arylglyoxal as starting material in Passerini and Ugi reactions affords βketoamides. This has allowed to study keto-enol tautomerism in these systems and assess theway in which the presence of acyloxy or aminoacyl groups bound to the C2 position affects suchtautomerism, and to investigate the reactivity of both the enol and carbonyl forms. In this work wealso prove the versatility of the Passerini reaction, since depending on the conditions to which thecorresponding adducts are subjected different products of synthetic interest can be obtained.
PB MDPI
YR 2021
FD 2021-02
LK http://hdl.handle.net/10259/8613
UL http://hdl.handle.net/10259/8613
LA eng
NO This research was funded by Consejería de Educación de la Junta de Castilla y León, project BU075G19.
DS Repositorio Institucional de la Universidad de Burgos
RD 04-dic-2024