RT info:eu-repo/semantics/article
T1 Headspace detection of ethanethiol in wine by cobalt phthalocyanine modified screen-printed carbon electrodes
A1 Portugal Gómez, Paula
A1 Domínguez Renedo, Olga
A1 Alonso Lomillo, Mª Asunción
K1 Ethanethiol
K1 Wine
K1 Amperometry
K1 Screen-printed carbon electrodes
K1 Headspace
K1 Química analítica
K1 Chemistry, Analytic
K1 Enología
K1 Wine and wine making
AB The formation of thiols has a notable and detrimental sensory impact, especially in the aroma of bottled wines. Their detection in wine is of great interest to avoid important economic and image losses for wineries. This work reports the study of different cobalt phthalocyanine/nanomaterials-based sensors for the headspace detection of volatile thiols. The amperometric procedure based on the use of carbon sensors simply modified with cobalt phthalocyanine showed the best performance. Under the optimum conditions of applied potential, +0.8 V, and pH of the supporting electrolyte, 2.6, this procedure shows a reproducibility of 7% (n = 5) in terms of relative standard deviation of the slopes of calibration curves built in the concentration range from 9.9 to 82.6 μg/L, a capability of detection of 12.5 μg/L and a decision limit of 6.5 μg/L (α = β = 0.05). The use of this electrocatalytic material and the headspace measurements reduce interferents, increasing the selectivity of the procedure, which allows the easy and successful quantification of ethanethiol in white and red wines.
PB Elsevier
SN 0039-9140
YR 2023
FD 2023-08-01
LK http://hdl.handle.net/10259/9263
UL http://hdl.handle.net/10259/9263
LA eng
NO Authors would like to acknowledge funding from Agencia Estatal de Investigación/Ministerio de Ciencia e Innovación (PID2020-117095RB-I00).
DS Repositorio Institucional de la Universidad de Burgos
RD 08-ene-2025