RT info:eu-repo/semantics/article T1 Boron nitride-reinforced porous aramid composites with enhanced mechanical performance and thermal conductivity A1 Rubio Aguinaga, Andrea A1 Reglero Ruiz, José Antonio A1 García Gómez, Alejandra A1 Peña Martín, Elisa A1 Ando, Shinji A1 Muñoz Santamaría, María Asunción A1 García Pérez, José Miguel A1 Trigo López, Miriam K1 Particle-reinforced composites K1 Mechanical properties K1 Elastic properties K1 Scanning electron microscopy (SEM) K1 Polymer solution casting K1 Química inorgánica K1 Chemistry, Inorganic K1 Materiales K1 Materials K1 Polímeros K1 Polymers AB Aramids are materials with high-performance properties and used in advanced applications, including bulletproof vests and aerospace industry components. Consequently, research is focused on improving their properties and reducing their density to achieve fuel reduction and enhanced comfort. Herein we describe the preparation of dense, micro, and nanoporous aramid films containing hexagonal boron nitride (hBN) with two objectives: improving mechanical performance and increasing thermal conductivity (TC) in porous films for specific applications. The preparation procedure is simple and scalable, involving the addition of hBN and a porosity promoter to control the porous structure in the film's casting solution. Tensile tests revealed that the inclusion of 10% of hBN in microporous aramids led to a 130% increase in Young's modulus and 63% reduction in material's density compared to the dense commercial aramid. The orientation of the hBN in the films was also evaluated by considering the XRD and the thermal properties of the films. The films containing hBN exhibited enhanced TC and thermal diffusivity (TD) together with a very low density and improved mechanical performance, which can benefit applications in the aerospace industry, protective equipment, and battery separators. PB Elsevier SN 0266-3538 YR 2023 FD 2023-09-29 LK http://hdl.handle.net/10259/9277 UL http://hdl.handle.net/10259/9277 LA eng NO This work was supported by the Regional Government of Castilla y León (Junta de Castilla y León), the Ministry of Science and Innovation MICIN and the European Union NextGenerationEU/PRTR, and the Spanish Agencia Estatal de Investigación (State Research Agency) (PID2019-108583RJ-I00/AEI/10.13039/501100011033). DS Repositorio Institucional de la Universidad de Burgos RD 17-jul-2024