RT info:eu-repo/semantics/article
T1 Synthesis of 1,4-ketoaldehydes and 1,4-diketones by Mo-catalyzed oxidative cleavage of cyclobutane-1,2-diols
A1 Gómez Gil, Sara
A1 Rubio Presa, Rubén
A1 Hernández Ruiz, Raquel
A1 Suárez Pantiga, Samuel
A1 Pedrosa Sáez, María de los Remedios
A1 Sanz Díez, Roberto
K1 Química orgánica
K1 Chemistry, Organic
K1 Biología molecular
K1 Molecular biology
AB A new two-step procedure for the synthesis of 1,4-dicarbonyls hasbeen developed involving an efficient and clean Mo-catalyzed oxidative cleavage of cyclobutane-1,2-diols with DMSO, which is usedas solvent and oxidant. The required starting glycols were preparedby nucleophilic additions of organolithiums and Grignard reagentsto easily available 2-hydroxycyclobutanones.
PB Royal Society of Chemistry
SN 1477-0520
YR 2023
FD 2023-04-26
LK http://hdl.handle.net/10259/9324
UL http://hdl.handle.net/10259/9324
LA eng
NO We gratefully acknowledge Ministerio de Ciencia e Innovación and FEDER (PID2020-115789GB-C21), and Junta de Castilla y León and FEDER (BU049P20) for financial support. S. G.-G. and R. H.-R. thank Ministerio de Educación for FPU predoctoral contracts. S. S.-P. thanks Ministerio de Ciencia e Innovación and “NextGenerationEU”/PRTR EU for a Ramón y Cajal contract (RYC2021-031533-I).
DS Repositorio Institucional de la Universidad de Burgos
RD 05-jul-2024