TY - JOUR AU - Vicente Poutás, Luis Carlos de AU - Castiñeira Reis, Marta AU - Sanz Díez, Roberto AU - Silva López, Carlos AU - Nieto Faza, Olalla . PY - 2016 SN - 0020-1669 UR - http://hdl.handle.net/10259/4273 AB - We propose a novel mechanism for the deoxydehydration (DODH) reaction of glycols catalyzed by a [Bu4N][VO2(dipic)] complex (dipic = pyridine-2,6-dicarboxylate) using triphenylphosphine as a reducing agent. Using density functional theory, we have... LA - eng PB - American Chemical Society KW - Chemistry, Organic KW - Química orgánica TI - A Radical Mechanism for the Vanadium-Catalyzed Deoxydehydration of Glycols ER -