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dc.contributor.authorSanjuán Cortázar, Ana María 
dc.contributor.authorMartínez Cuezva, Alberto 
dc.contributor.authorGarcía García, Patricia
dc.contributor.authorFernández Rodríguez, Manuel A. 
dc.contributor.authorSanz Díez, Roberto 
dc.date.accessioned2015-07-27T11:30:48Z
dc.date.available2015-07-27T11:30:48Z
dc.date.issued2013-10
dc.identifier.issn1860-5397
dc.identifier.urihttp://hdl.handle.net/10259/3800
dc.description.abstractThe cyclization of o-(alkynyl)-3-(methylbut-2-enyl)benzenes, 1,6-enynes having a condensed aromatic ring at C3–C4 positions, has been studied under the catalysis of cationic gold(I) complexes. The selective 6-endo-dig mode of cyclization observed for the 7-substituted substrates in the presence of water or methanol giving rise to hydroxy(methoxy)-functionalized dihydronaphthalene derivatives is highly remarkable in the context of the observed reaction pathways for the cycloisomerizations of 1,6-enynes bearing a trisubstituted olefinen
dc.description.sponsorshipMinisterio de Ciencia e Innovación (MICINN) and FEDER (CTQ2010-15358)
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherBeilstein-Instituten
dc.relation.ispartofBeilstein Journal of Organic Chemistry, 2013. V. 9, p. 2242–2249en
dc.relation.ispartofseriesGold catalysis for organic synthesis II
dc.rightsAttribution 4.0 International
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectcatalysisen
dc.subjectdihydronaphthalenesen
dc.subjectgolden
dc.subjectgold catalysisen
dc.subjecthydroxycyclizationen
dc.subjectselectivityen
dc.subject.otherQuímica orgánicaen
dc.subject.otherChemistry, Organicen
dc.titleGold(I)-catalyzed 6-endo hydroxycyclization of 7-substituted-1,6-enynesen
dc.typeinfo:eu-repo/semantics/article
dc.rights.holderEste documento está sujeto a una licencia de uso Creative Commons, por la cual está permitido hacer copia, distribuir, comunicar públicamente, remezclar, transformar y crear a partir del material para cualquier finalidad, incluso comercial, siempre que se cite al autor original, se proporcione un enlace a la licencia y se indique si se han realizado cambios
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttp://dx.doi.org/10.3762/Fbjoc.9.263
dc.identifier.doi10.3762/Fbjoc.9.263
dc.relation.projectIDinfo:eu-repo/grantAgreement/FEDER/CTQ2010-15358
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersionen


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