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| dc.contributor.author | Sanjuán Cortázar, Ana María | |
| dc.contributor.author | Martínez Cuezva, Alberto | |
| dc.contributor.author | García García, Patricia | |
| dc.contributor.author | Fernández Rodríguez, Manuel A. | |
| dc.contributor.author | Sanz Díez, Roberto | |
| dc.date.accessioned | 2015-07-27T11:30:48Z | |
| dc.date.available | 2015-07-27T11:30:48Z | |
| dc.date.issued | 2013-10 | |
| dc.identifier.issn | 1860-5397 | |
| dc.identifier.uri | http://hdl.handle.net/10259/3800 | |
| dc.description.abstract | The cyclization of o-(alkynyl)-3-(methylbut-2-enyl)benzenes, 1,6-enynes having a condensed aromatic ring at C3–C4 positions, has been studied under the catalysis of cationic gold(I) complexes. The selective 6-endo-dig mode of cyclization observed for the 7-substituted substrates in the presence of water or methanol giving rise to hydroxy(methoxy)-functionalized dihydronaphthalene derivatives is highly remarkable in the context of the observed reaction pathways for the cycloisomerizations of 1,6-enynes bearing a trisubstituted olefin | en |
| dc.description.sponsorship | Ministerio de Ciencia e Innovación (MICINN) and FEDER (CTQ2010-15358) | |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | es |
| dc.publisher | Beilstein-Institut | en |
| dc.relation.ispartof | Beilstein Journal of Organic Chemistry, 2013. V. 9, p. 2242–2249 | en |
| dc.relation.ispartofseries | Gold catalysis for organic synthesis II | |
| dc.rights | Attribution 4.0 International | |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
| dc.subject | catalysis | en |
| dc.subject | dihydronaphthalenes | en |
| dc.subject | gold | en |
| dc.subject | gold catalysis | en |
| dc.subject | hydroxycyclization | en |
| dc.subject | selectivity | en |
| dc.subject.other | Química orgánica | en |
| dc.subject.other | Chemistry, Organic | en |
| dc.title | Gold(I)-catalyzed 6-endo hydroxycyclization of 7-substituted-1,6-enynes | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.rights.holder | Este documento está sujeto a una licencia de uso Creative Commons, por la cual está permitido hacer copia, distribuir, comunicar públicamente, remezclar, transformar y crear a partir del material para cualquier finalidad, incluso comercial, siempre que se cite al autor original, se proporcione un enlace a la licencia y se indique si se han realizado cambios | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.relation.publisherversion | http://dx.doi.org/10.3762/Fbjoc.9.263 | |
| dc.identifier.doi | 10.3762/Fbjoc.9.263 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/FEDER/CTQ2010-15358 | |
| dc.type.hasVersion | info:eu-repo/semantics/publishedVersion | en |
