Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/3801
Título
Synthesis of 2-Indol-3-ylbenzofulvenes through a Tandem Reaction Catalyzed by Cationic Gold(I) Complexes
Autor
Publicado en
Synthesis. 2012, V. 44, n. 12, p. 1874-1884
Editorial
Georg Thieme Verlag
Fecha de publicación
2012
ISSN
0039-7881
DOI
10.1055/s-0031-1290950
Abstract
A new access to benzofulvenes bearing an indol-3-yl substituent at C-2 has been developed. Treatment of 3-propargylindoles possessing an additional hydroxy group at the other propargylic position with a cationic gold(I) complex triggers a tandem 1,2-indole migration/aura-iso-Nazarov cyclization/elimination sequence that takes place under mild conditions
Palabras clave
benzofulvenes
catalysis
gold
indoles
tandem reactions
Materia
Química orgánica
Chemistry, Organic
Versión del editor
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