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dc.contributor.authorIbáñez Martínez, David 
dc.contributor.authorPlana, Daniela .
dc.contributor.authorHeras Vidaurre, Aránzazu 
dc.contributor.authorFermín, David J. .
dc.contributor.authorColina Santamaría, Álvaro 
dc.date.accessioned2015-09-29T09:36:28Z
dc.date.available2015-09-29T09:36:28Z
dc.date.issued2015-05
dc.identifier.issn1388-2481
dc.identifier.urihttp://hdl.handle.net/10259/3856
dc.description.abstractIn-situ Raman spectroscopy is implemented for the first time to monitor dynamic charge transfer processes at polarisable interfaces between two immiscible electrolyte solutions (ITIES) in real time. A custom-designed new electrochemical cell is described which allows probing the Raman signals of ferroin ions as a function of the potential applied across the water|1,2-dichlorobenzene (DCB) interface. This approach is also used for investigating the heterogeneous electron transfer reaction involving dimethylferrocene in DCB and potassium hexacyanoferrate (II/III) in the aqueous phase. The evolution of the Raman signals during potentiodynamic measurements is recorded in real-time with a resolution of a few seconds.en
dc.description.sponsorshipJunta de Castilla y Leon (GR71, BU349-U13) and Ministerio de Economia y Competitividad (CTQ2010-17127) is gratefully acknowledged. D.I. thanks Ministerio de Economia y Competitividad for his predoctoral FPI fellowship. D.P. and D.J.F. acknowledge financial support from the EPSRC (grant EP/K007025/1)en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherElsevieren
dc.relation.ispartofElectrochemistry Communications. 2015, V. 54, p. 14–17en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectLiquid/liquid interfacesen
dc.subjectIon transferen
dc.subjectElectron transferen
dc.subjectIn-situ Raman spectroscopyen
dc.subject.otherQuímica analíticaes
dc.subject.otherChemistry, Analyticen
dc.titleMonitoring charge transfer at polarisable liquid/liquid interfaces employing time-resolved Raman spectroelectrochemistryen
dc.typeinfo:eu-repo/semantics/article
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.elecom.2015.02.012
dc.identifier.doi10.1016/j.elecom.2015.02.012
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU349-U13
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/CTQ2010-17127
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/GR71
dc.type.hasVersioninfo:eu-repo/semantics/submittedVersionen


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