| dc.contributor.author | Sanjuán Cortázar, Ana María | |
| dc.contributor.author | García García, Patricia | |
| dc.contributor.author | Fernández Rodríguez, Manuel A. | |
| dc.contributor.author | Sanz Díez, Roberto | |
| dc.date.accessioned | 2015-12-10T10:56:51Z | |
| dc.date.available | 2015-12-10T10:56:51Z | |
| dc.date.issued | 2013-07 | |
| dc.identifier.issn | 1615-4150 | |
| dc.identifier.uri | http://hdl.handle.net/10259/3893 | |
| dc.description.abstract | An asymmetric synthesis of elusive chiral cyclopentadienes has been developed by gold(I)-catalyzed alkoxycyclization of 1,3-dien-5-ynes. The application of these substrates in completely diastereoselective Diels–Alder cycloaddition reactions, which can be carried out in one pot from achiral 1,3-dien-5-ynes, allows the preparation of highly functionalized products bearing five stereogenic centers with high enantiomeric excesses | en |
| dc.description.sponsorship | Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021A09 and GR-172) for financial support. A. M. S. thanks Junta de Castilla y Leon (Consejeria de Educacion) and Fondo Social Europeo for a PIRTU contract. P. G.-G. and M. A. F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | es |
| dc.publisher | Wiley-VCH Verlag | en |
| dc.relation.ispartof | Advanced Synthesis & Catalysis. 2013, V. 355, n. 10, p. 1955–1962 | en |
| dc.subject | cycloisomerization | en |
| dc.subject | cyclopentadienes | en |
| dc.subject | Diels–Alder reaction | en |
| dc.subject | dienynes | en |
| dc.subject | gold | en |
| dc.subject.other | Química orgánica | es |
| dc.subject.other | Chemistry, Organic | en |
| dc.title | Enantioselective Synthesis of Cyclopentadienes by Gold(I)- Catalyzed Cyclization of 1,3-Dien-5-ynes | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.description.version | This is the peer reviewed version of the following article: Sanjuán, A. M., García-García, P., Fernández-Rodríguez, M. A. and Sanz, R. (2013), Enantioselective Synthesis of Cyclopentadienes by Gold(I)- Catalyzed Cyclization of 1,3-Dien-5-ynes. Adv. Synth. Catal., 355: 1955–1962. doi: 10.1002/adsc.201300448, which has been published in final form at 10.1002/adsc.201300448. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.relation.publisherversion | http://dx.doi.org/10.1002/adsc.201300448 | |
| dc.identifier.doi | 10.1002/adsc.201300448 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICINN/CTQ2010-15358 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU | |
| dc.relation.projectID | info:eu-repo/grantAgreement/JCyL/BU021A09 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/JCyL/GR-172 | |
| dc.type.hasVersion | info:eu-repo/semantics/acceptedVersion | en |
