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| dc.contributor.author | García García, Patricia | |
| dc.contributor.author | Martínez Cuezva, Alberto | |
| dc.contributor.author | Sanjuán Cortázar, Ana María | |
| dc.contributor.author | Fernández Rodríguez, Manuel A. | |
| dc.contributor.author | Sanz Díez, Roberto | |
| dc.date.accessioned | 2016-01-20T12:31:52Z | |
| dc.date.available | 2016-01-20T12:31:52Z | |
| dc.date.issued | 2011-08 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.uri | http://hdl.handle.net/10259/3908 | |
| dc.description.abstract | Highly substituted benzene derivatives have been easily prepared in a regioselective way from readily available 1,3-hexadien-5-ynes through a gold(I)-catalyzed tandem reaction. The process involves an initial cyclization followed by a selective Wagner-Meerwein shift in which the migration preference seems to be determined by the ability to stabilize a positive charge | en |
| dc.description.sponsorship | Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021A09 and GR-172) for financial suport. A.M. S. thanks Junta de Castilla y Leon for a predoctoral fellowship. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts | en |
| dc.description.sponsorship | Ministerio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021A09 and GR-172) for financial suport. A.M. S. thanks Junta de Castilla y Leon for a predoctoral fellowship. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts | |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | es |
| dc.publisher | American Chemical Society | en |
| dc.relation.ispartof | Organic Letters. 2011, V. 13, n. 18, p. 4970-4973 | en |
| dc.subject.other | Química orgánica | es |
| dc.subject.other | Chemistry, Organic | en |
| dc.title | Gold(I)-Catalyzed Tandem Cyclization–Selective Migration Reaction of 1,3-Dien-5-ynes: Regioselective Synthesis of Highly Substituted Benzenes | en |
| dc.title | info:eu-repo/semantics/acceptedVersion | |
| dc.type | info:eu-repo/semantics/article | |
| dc.description.version | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic letters, copyright © American Chemical Society after peer review and technical editing by the publisher. | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.relation.publisherversion | http://dx.doi.org/10.1021/ol202129n | |
| dc.identifier.doi | 10.1021/ol202129n | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICINN/CTQ2010-15358 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU | |
| dc.relation.projectID | info:eu-repo/grantAgreement/JCyL/BU021A09 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/JCyL/GR-172 |
