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dc.contributor.authorGarcía Bartolomé, Nuria 
dc.contributor.authorRubio Presa, Rubén 
dc.contributor.authorGarcía García, Patricia
dc.contributor.authorFernández Rodríguez, Manuel A. 
dc.contributor.authorPedrosa Sáez, María de los Remedios 
dc.contributor.authorArnáiz García, Francisco Javier 
dc.contributor.authorSanz Díez, Roberto 
dc.date.accessioned2016-12-01T11:24:42Z
dc.date.available2017-04-21T02:45:06Z
dc.date.issued2016-04
dc.identifier.issn1463-9262
dc.identifier.urihttp://hdl.handle.net/10259/4289
dc.description.abstractA catalytic methodology for the oxidative cleavage of vicinal diols is described as an advantageous alternative in terms of the environmental impact on classical methods involving toxic oxidants. The novel strategy is based on the use of dioxomolybdenum(VI) complexes as catalysts and dimethyl sulfoxide (DMSO) as an oxidant and displays high selectivity and a broad scope for glycol cleavage. In addition, the developed system is also useful for the oxidation of acyloins to diketones.en
dc.description.sponsorshipMinisterio de Economía y Competitividad (MINECO) and FEDER (CTQ2013-48937-C2-1-P) and Junta de Castilla y León (BU237U13)en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherRoyal Society of Chemistryen
dc.relation.ispartofGreen Chemistry. 2016, V. 18, n. 8, p. 2335-2340en
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.titleA Selective, Efficient and Environmentally Friendly Method for the Oxidative Cleavage of Glycolsen
dc.typeinfo:eu-repo/semantics/article
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttp://dx.doi.org/10.1039/c5gc02862k
dc.identifier.doi10.1039/c5gc02862k
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO-FEDER/CTQ2013-48937-C2-1-P
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU237U13
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen


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