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dc.contributor.authorRubio Presa, Rubén 
dc.contributor.authorFernández Rodríguez, Manuel A. 
dc.contributor.authorPedrosa Sáez, María de los Remedios 
dc.contributor.authorArnáiz García, Francisco Javier 
dc.contributor.authorSanz Díez, Roberto 
dc.date.accessioned2017-07-13T09:28:47Z
dc.date.available2018-05-17T02:45:07Z
dc.date.issued2017-05
dc.identifier.issn1615-4150
dc.identifier.urihttp://hdl.handle.net/10259/4528
dc.description.abstractA molybdenum-catalyzed deoxygenationof pyridine N -oxides and N-hydroxybenzotriazoles,as well as other azole N-oxides, has been developedusing pinacol as an environmentally friendly oxo-acceptor. The only by-products are acetone andwater making the process a convenient alternativeto established protocols in terms of waste gener-ation. The reaction is highly chemose lective and avariety of functional groups are tolerated. Theprocesses are usually very clean allowing theisolation of the pure deoxygenated products after asimple extraction in most cases.en
dc.description.sponsorshipMinisterio de Economı´ayCompetitividad (MINECO) (CTQ2013-48937-C2-1-P,CTQ2015-70371-REDT, and CTQ2016-75023-C2-1-P) andJunta de Castilla y Leo´n and FEDER (BU076U16)en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherWiley-VCH Verlagen
dc.relation.ispartofAdvanced Synthesis & Catalysis. 2017, V. 359, n. 10, p. 1752–1757en
dc.subjectamine N-oxidesen
dc.subjectdeoxygenationen
dc.subjectmolyb-denumen
dc.subjectmicrowave heatingen
dc.subjectN-hydroxybenzotria-zolesen
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.titleMolybdenum-catalyzed deoxygenation of heteroaromatic n-oxides and hydroxides using Pinacol as Reducing Agenten
dc.typeinfo:eu-repo/semantics/article
dc.description.versionThis is the peer reviewed version of the following article: R. Rubio-Presa, M. A. Fernández-Rodríguez, M. R. Pedrosa, F. J. Arnáiz, R. Sanz, Adv. Synth. Catal. 2017, 359, 1752. doi: 10.1002/adsc.201700071, which has been published in final form at 10.1002/adsc.201700071. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttp://dx.doi.org/10.1002/adsc.201700071
dc.identifier.doi10.1002/adsc.201700071
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen


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