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dc.contributor.authorFeberero García, Claudia 
dc.contributor.authorSuárez Pantiga, Samuel 
dc.contributor.authorCabello Fernández, Zaida 
dc.contributor.authorSanz Díez, Roberto 
dc.date.accessioned2018-09-07T10:42:31Z
dc.date.available2019-04-20T02:45:07Z
dc.date.issued2018-04
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/10259/4925
dc.description.abstractThe reaction of o-lithiated O-aryl N,N-diethylcarbamates with (hetero)aromatic nitriles gives rise to functionalized salicylidene urea derivatives in high yields through a new 1,5-O → N carbamoyl migration. This Snieckus–Fries-type rearrangement nicely complements previously known O → C and O → O related shifts. In addition, when dimethylmalononitrile is used as the electrophilic partner, the carbamoyl shift is preferred over the expected transnitrilation reaction.en
dc.description.sponsorshipJunta de Castilla y León and FEDER (BU076U16) and Ministerio de Economía y Competitividad (MINECO) and FEDER (CTQ2016-48937-C2-1-P)en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherAmerican Chemical Societyen
dc.relation.ispartofOrganic Letters. 2018, V. 20, n. 8, p. 2437–2440en
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.title1,5-O → N Carbamoyl Snieckus–Fries-Type Rearrangementen
dc.typeinfo:eu-repo/semantics/article
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttps://doi.org/10.1021/acs.orglett.8b00782
dc.identifier.doi10.1021/acs.orglett.8b00782
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU076U16
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/CTQ2016-48937-C2-1-P
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen


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