Afficher la notice abrégée

dc.contributor.authorTrigueros Andrés, Ester 
dc.contributor.authorSanz Díez, Mª Teresa 
dc.contributor.authorAlonso Riaño, Patricia 
dc.contributor.authorBeltrán Calvo, Sagrario 
dc.contributor.authorRamos Rodríguez, Cipriano 
dc.contributor.authorMelgosa Gómez, Rodrigo 
dc.date.accessioned2021-10-15T10:27:19Z
dc.date.available2021-10-15T10:27:19Z
dc.date.issued2021
dc.identifier.issn0921-8971
dc.identifier.urihttp://hdl.handle.net/10259/6027
dc.description.abstractIn this work valorization of the underexploited industrial solid residue generated after agar extraction from Gelidium sesquipedale was studied by using subcritical water in a semicontinuous fix-bed reactor. First, a complete characterization of this by-product was carried out, determining up to 21%(w/w) of protein content (for a nitrogen factor of 4.9) with high content of essential amino acids, 37% (w/w) of carbohydrate fraction and high amount of ash, 22% (w/w). The effect of temperature, in the range from 129 to 200 °C, and flow rate, in the range from 2 to 6 mL min−1, on protein and carbon fraction extraction/hydrolysiswas studied.At constant flow rate of 2 mL min−1, a maximum in the protein extraction was achieved at 185 °C. Higher temperatures led to degradation of protein or its hydrolysis products. Free amino acids release followed the same trend as the protein fraction. The most temperature sensitive amino acids, as determined by gas chromatography (EZ:faast Phenomenex), were serine and aspartic and glutamic acids. As a consequence, the selectivity towards non-polar amino acids increased by working at high severity factors. A Pearson correlation between antioxidant capacity of the collected extracts with the bioactive compounds determined in the extracts (total polyphenolic compounds –TPC-, peptides and free amino acids) was established, being stronger for TPC. The ash content in the solid residue after treatment steadily increased with temperature due to non-solubilization being possible its application in agriculture as fertilizers.en
dc.description.sponsorshipAgencia Estatal de Investigación [grant number PID2019-104950RB-I00 / AEI / https://doi.org/10.13039/501100011033] and the Junta de Castilla y León (JCyL) and the European Regional Development Fund (ERDF) [grant number BU301P18 and BU050P20]es
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherSpringeres
dc.relation.ispartofJournal of Applied Phycology. 2021, V. 33, n. 2, p. 1181–1194es
dc.subjectSubcritical water extractionen
dc.subjectBiorefineryen
dc.subjectMacroalgae residueen
dc.subjectProteinen
dc.subjectAmino acidsen
dc.subjectAntioxidant activityen
dc.subject.otherIngeniería químicaes
dc.subject.otherChemical engineeringen
dc.titleRecovery of the protein fraction with high antioxidant activity from red seaweed industrial solid residue after agar extraction by subcritical water treatmenten
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.1007/s10811-020-02349-0es
dc.identifier.doi10.1007/s10811-020-02349-0
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/PID2019-104950RB-I00-AEI-10.13039-501100011033
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU301P18
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU050P20
dc.identifier.essn1573-5176
dc.journal.titleJournal of Applied Phycologyes
dc.volume.number33es
dc.issue.number2es
dc.page.initial1181es
dc.page.final1194es
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones


Fichier(s) constituant ce document

Thumbnail

Ce document figure dans la(les) collection(s) suivante(s)

Afficher la notice abrégée