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dc.contributor.authorGarcía Tojal, Javier 
dc.contributor.authorCuevas Vicario, José Vicente 
dc.contributor.authorRojo Cámara, Mª Josefa 
dc.contributor.authorDíaz de Greñu Puertas, Borja 
dc.contributor.authorHernando Muñoz, Carla 
dc.contributor.authorGarcía Calvo, José 
dc.contributor.authorMartín Salgado, Mateo
dc.contributor.authorTorroba Pérez, Tomás 
dc.date.accessioned2021-11-11T13:52:56Z
dc.date.available2021-11-11T13:52:56Z
dc.date.issued2021-03
dc.identifier.issn1420-3049
dc.identifier.urihttp://hdl.handle.net/10259/6139
dc.description.abstractWe describe the synthesis of fluorogenic arylureas and amides and their interaction with primary or secondary amines under air and light in organic-aqueous mixtures to give rise to a new class of persistent organic radicals, described on the basis of their electron paramagnetic resonance (EPR), as well as UV–vis, fluorescence, NMR, and quantum mechanics calculations, and their prospective use as multi-signal reporters in a smart label for fish freshness.en
dc.description.sponsorshipFunded by the NATO Science for Peace and Security Programme (Grant SPS G5536), the Junta de Castilla y León, Consejería de Educación y Cultura y Fondo Social Europeo (Grant BU263P18), and the Ministerio de Ciencia e Innovación (Grant PID2019-111215RB-100)en
dc.format.mimetypeapplication/pdf
dc.language.isoengen
dc.publisherMDPIen
dc.relation.ispartofMolecules. 2021, V. 26, n. 5, 1404en
dc.rightsAtribución 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectArylureasen
dc.subjectTurn-on fluorescenceen
dc.subjectOrganic radicalsen
dc.subjectSmart labelen
dc.subjectVolatile aminesen
dc.subject.otherQuímicaes
dc.subject.otherChemistryen
dc.titleSynthesis of Fluorogenic Arylureas and Amides and Their Interaction with Amines: A Competition between Turn-on Fluorescence and Organic Radicals on the Way to a Smart Label for Fish Freshnessen
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.3390/molecules26051404es
dc.identifier.doi10.3390/molecules26051404
dc.relation.projectIDinfo:eu-repo/grantAgreement/NATO/Science for Peace and Security Programme/G5536//Development of New Chemical Sensors and Optical Technologies for Fast and Sensitive Detection of Improvised Explosivesen
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Castilla y León//BU263P18//Sondas fluorescentes en materiales nanoestructurados para la detección y modificación de toxinas medioambientales o contaminantes traza y su incorporación a estrategias terapéuticas [fluonano]es
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-111215RB-I00/ES/DESARROLLO DE NUEVOS SENSORES QUIMICOS PARA LA DETECCION RAPIDA Y SELECTIVA DE DISPOSITIVOS EXPLOSIVOS IMPROVISADOSes
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones


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