| dc.contributor.author | Fernández-Fariña, Sandra | |
| dc.contributor.author | González-Barcia, Luis M. | |
| dc.contributor.author | Romero, María J. | |
| dc.contributor.author | García Tojal, Javier | |
| dc.contributor.author | Maneiro, Marcelino | |
| dc.contributor.author | Seco, José M. | |
| dc.contributor.author | Zaragoza, Guillermo | |
| dc.contributor.author | Martínez-Calvo, Miguel | |
| dc.contributor.author | González-Noya, Ana M. | |
| dc.contributor.author | Pedrido Castiñeiras, Rosa | |
| dc.date.accessioned | 2022-03-03T12:16:11Z | |
| dc.date.available | 2022-03-03T12:16:11Z | |
| dc.date.issued | 2022-02 | |
| dc.identifier.uri | http://hdl.handle.net/10259/6426 | |
| dc.description.abstract | We present the first example of a silver double-tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate [Ag2(H2L)2]SO4. This is the first silver mediated desulfurization reaction. | en |
| dc.description.sponsorship | FEDER cofunded-grants: from Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia, 2017 GRC GI-1682 (ED431C 2017/01), 2018 GRC GI-1584 (ED431C 2018/13), MetalBIO Network (ED431D 2017/01), Ministerio de Ciencia, Innovación y Universidades, METALBIO (CTQ2017-90802-REDT) and MultiMetDrugs (RED2018-102471-T). | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | en |
| dc.publisher | Royal Society of Chemistry | en |
| dc.relation.ispartof | Inorganic Chemistry Frontiers. 2022, V. 9, n. 3, p. 531-536 | en |
| dc.subject.other | Química inorgánica | es |
| dc.subject.other | Chemistry, Inorganic | en |
| dc.title | Conversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process | en |
| dc.type | info:eu-repo/semantics/article | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.relation.publisherversion | https://doi.org/10.1039/D1QI01308D | es |
| dc.identifier.doi | 10.1039/d1qi01308d | |
| dc.relation.projectID | info:eu-repo/grantAgreement/Xunta de Galicia//ED431C 2017%2F01 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/Xunta de Galicia//ED431C 2018%2F13 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/Xunta de Galicia//ED431D 2017%2F01 | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICIU//CTQ2017-90802-REDT | |
| dc.relation.projectID | info:eu-repo/grantAgreement/MICIU//RED2018-102471-T | |
| dc.identifier.essn | 2052-1553 | |
| dc.journal.title | Inorganic Chemistry Frontiers | en |
| dc.volume.number | 9 | es |
| dc.issue.number | 3 | es |
| dc.page.initial | 531 | es |
| dc.page.final | 536 | es |
| dc.type.hasVersion | info:eu-repo/semantics/acceptedVersion | es |
