Ver item 

Mostrar registro simples

dc.contributor.authorFernández-Fariña, Sandra
dc.contributor.authorGonzález-Barcia, Luis M.
dc.contributor.authorRomero, María J.
dc.contributor.authorGarcía Tojal, Javier 
dc.contributor.authorManeiro, Marcelino
dc.contributor.authorSeco, José M.
dc.contributor.authorZaragoza, Guillermo
dc.contributor.authorMartínez-Calvo, Miguel
dc.contributor.authorGonzález-Noya, Ana M.
dc.contributor.authorPedrido Castiñeiras, Rosa
dc.date.accessioned2022-03-03T12:16:11Z
dc.date.available2022-03-03T12:16:11Z
dc.date.issued2022-02
dc.identifier.urihttp://hdl.handle.net/10259/6426
dc.description.abstractWe present the first example of a silver double-tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate [Ag2(H2L)2]SO4. This is the first silver mediated desulfurization reaction.en
dc.description.sponsorshipFEDER cofunded-grants: from Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia, 2017 GRC GI-1682 (ED431C 2017/01), 2018 GRC GI-1584 (ED431C 2018/13), MetalBIO Network (ED431D 2017/01), Ministerio de Ciencia, Innovación y Universidades, METALBIO (CTQ2017-90802-REDT) and MultiMetDrugs (RED2018-102471-T).en
dc.format.mimetypeapplication/pdf
dc.language.isoengen
dc.publisherRoyal Society of Chemistryen
dc.relation.ispartofInorganic Chemistry Frontiers. 2022, V. 9, n. 3, p. 531-536en
dc.subject.otherQuímica inorgánicaes
dc.subject.otherChemistry, Inorganicen
dc.titleConversion of a double-tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization processen
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.1039/D1QI01308Des
dc.identifier.doi10.1039/d1qi01308d
dc.relation.projectIDinfo:eu-repo/grantAgreement/Xunta de Galicia//ED431C 2017%2F01
dc.relation.projectIDinfo:eu-repo/grantAgreement/Xunta de Galicia//ED431C 2018%2F13
dc.relation.projectIDinfo:eu-repo/grantAgreement/Xunta de Galicia//ED431D 2017%2F01
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICIU//CTQ2017-90802-REDT
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICIU//RED2018-102471-T
dc.identifier.essn2052-1553
dc.journal.titleInorganic Chemistry Frontiersen
dc.volume.number9es
dc.issue.number3es
dc.page.initial531es
dc.page.final536es
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones


Arquivos deste item

Thumbnail
Nome:
Fernandez-icf_2022.pdf
Tamanho:
1.418Mb
Formato:
Adobe PDF
Visualizar/Abrir

Este item aparece na(s) seguinte(s) coleção(s)

Mostrar registro simples