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dc.contributor.authorVelasco Pérez, Noelia 
dc.contributor.authorMartínez Núñez, Clara 
dc.contributor.authorFernández Rodríguez, Manuel A. 
dc.contributor.authorSanz Díez, Roberto 
dc.contributor.authorSuárez Pantiga, Samuel 
dc.date.accessioned2023-02-07T12:10:37Z
dc.date.available2023-02-07T12:10:37Z
dc.date.issued2022-07
dc.identifier.issn1615-4150
dc.identifier.urihttp://hdl.handle.net/10259/7413
dc.description.abstractA tandem 1,3-sulfur migration followed by iodocyclization reaction of propargylic sulfides in the presence of NIS in HFIP has been developed to synthesize indene-based β-iodoalkenyl sulfides. The choice of the reaction media is crucial to promote the reaction. The proposed mechanism involving the initial NIS activation by HFIP and favoring the sulfur migration of the starting propargylic thioether via cationic intermediates is experimentally supported. In addition, the suitability of selected indene-based β-iodoalkenyl sulfides as building blocks for subsequent C C bond-forming reactions has been demonstrated.en
dc.description.sponsorshipWe gratefully acknowledge MICINN (PID2020-115789GBC21); and “NextGenerationEU/PRTR” (PDC2021-120825- C21), and Junta de Castilla y León and FEDER (BU049P20) for financial support. The project leading to these results has also received funding from “la Caixa” Foundation, under the Agreement LCF/PR/PR18/51130007> (CAIXA-UBU001). N.V. and S.S.-P. thank Junta de Castilla y León (Consejería de Educación) and Fondo Social Europeo for predoctoral (N.V) and postdoctoral (S.S.-P.) contracts, respectively.en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherWileyen
dc.relation.ispartofAdvanced Synthesis & Catalysis. 2022, V. 364, n. 17, p. 2932-2938es
dc.rightsAtribución-NoComercial 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.subjectSynthetic methodsen
dc.subjectSulfuren
dc.subjectAlkenesen
dc.subjectAlkynesen
dc.subjectHalogensen
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.titleNIS/HFIP‐Mediated Synthesis of Indene‐Based β‐Iodoalkenyl Sulfides from Propargylic Sulfidesen
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.1002/adsc.202200613es
dc.identifier.doi10.1002/adsc.202200613
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115789GB-C21/ES/ESTRATEGIAS SINTETICAS SOSTENIBLES PARA LA TRANSFORMACION DIRECTA DE NITROCOMPUESTOS Y DESARROLLO DE NUEVAS REACCIONES CATALIZADAS POR ORO/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PDC2021-120825-C21/ES/Valorización de productos de la biomasa por catálisis con complejos de dioxomolibdeno/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Castilla y León//BU049P20//Estrategias sintéticas sostenibles para la halogenación directa de nitrocompuestos y la preparación de electrolitos orgánicos para baterías de flujo redox/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/Fundación Bancaria Caixa d'Estalvis i Pensions de Barcelona//LCF%2FPR%2FPR18%2F51130007// Fluoración Directa de Nitrocompuestos y Sales de Heteroaril Fosfonio: Síntesis de Fluorocompuestos/FluNitroPhos/es
dc.identifier.essn1615-4169
dc.journal.titleAdvanced Synthesis & Catalysisen
dc.volume.number364es
dc.issue.number17es
dc.page.initial2932es
dc.page.final2938es
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones


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