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dc.contributor.authorAlonso Riaño, Patricia 
dc.contributor.authorAmândio, Mariana S.T.
dc.contributor.authorXavier, Ana María Rebelo Barreto
dc.contributor.authorBeltrán Calvo, Sagrario 
dc.contributor.authorSanz Díez, Mª Teresa 
dc.date.accessioned2023-03-10T10:59:50Z
dc.date.available2023-03-10T10:59:50Z
dc.date.issued2022-11
dc.identifier.urihttp://hdl.handle.net/10259/7526
dc.description.abstractBioeconomy and environmental issues envisage industrial by-products such as Brewer’s spent grain (BSG) as renewable resources for their recycling and reuse within a biorefinery concept. This study aimed to investigate the production of bioethanol from subcritical water (subW) pretreated BSG, following the conversion of the BSG biopolymers cellulose and hemicelluloses. The subW pretreatment was performed in a batch reactor at 174 ◦C, during 60 min and 5% (w/v) of dry BSG charge. The behavior of BSG biopolymers under subW pretreatment was monitored by evaluating the chemical composition of the liquid and solid streams and the chemical and structural changes caused in the solid residues by scanning electron microscope (SEM), CHNS elemental analysis and water retention value (WRV). The production of bioethanol from subW-pretreated BSG was assessed by separate hydrolysis and fermentation (SHF) and also by simultaneous saccharification and fermentation (SSF) by using the enzymatic cocktail Celluclast 1.5 L (40 FPU/gsolids) and the yeast Ethanol Red®. The higher bioethanol productivity (1.073 g·L −1 ·h −1 ) and concentration (32.18 g/L) were achieved by SSF with higher solids’ loading (25%) and following a fed-batch strategy. These results suggest that subcritical water pretreatment is a promising technology for the valorization of BSG as a feedstock for second-generation bioethanol production.en
dc.description.sponsorshipThis work was supported by the Agencia Estatal de Investigación (ES) [grant numbers PID2019–104950RB-I00/AEI/10.13039/501100011033, TED2021–129311B-I00 and PDC2022–133443-I00] and the Junta de Castilla y León (JCyL) and the European Regional Development Fund (ERDF) [grant number BU050P20]. The P. Alonso-Riaño predoctoral contract was funded by JCyL and the European Social Fund (ESF) by ORDEN EDU/556/2019, de 5 de junio. This work was also developed within the scope of the project CICECO-Aveiro Institute of Materials (PT), UIDB/50011/2020, UIDP/50011/2020 & LA/P/0006/2020, financed by national funds through the FCT/MEC (PIDDAC).en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherMDPIen
dc.relation.ispartofPolymers. 2022, V. 14, n. 23, 5218en
dc.rightsAtribución 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectSubcritical water pretreatmenten
dc.subjectBrewer's spent grainen
dc.subjectLignocellulosic biomassen
dc.subjectHigh solids' loadingen
dc.subjectSimultaneous saccharification and fermentationen
dc.subjectSeparate hydrolysis and fermentationen
dc.subject.otherIngeniería químicaes
dc.subject.otherChemical engineeringen
dc.titleSubcritical Water as Pretreatment Technique for Bioethanol Production from Brewer’s Spent Grain within a Biorefinery Concepten
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.3390/polym14235218es
dc.identifier.doi10.3390/polym14235218
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-104950RB-I00/ES/VALORIZACION DE SUBPRODUCTOS MARINOS MEDIANTE TECNOLOGIAS DE FLUIDOS SUB- Y SUPERCRITICOS PARA LA OBTENCION DE BIOCOMPUESTOS VALIOSOS/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica, Técnica y de Innovación 2021-2023/TED2021-129311B-I00/ES/Tecnologías verdes basadas en el empleo de fluidos presurizados para valorizar biomasa lignocelulósica mediante la producción de furfural/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica, Técnica y de Innovación 2021-2023/PDC2022-133443-I00/ES/Diseño de un prototipo para la extracción de bioproductos con agua subcrítica/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Castilla y León//BU050P20//Valorización de la fracción proteica de subproductos de la industria agroalimentaria de Castilla y León mediante tecnologías de fluidos presurizados/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/FCT//UIDP%2F50011%2F2020/PT/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/FCT//LA%2FP%2F0006%2F2020/PT/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/FCT//UIDB%2F50011%2F2020/PT/es
dc.identifier.essn2073-4360
dc.journal.titlePolymersen
dc.volume.number14es
dc.issue.number23es
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones


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