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dc.contributor.authorPérez Estébanez, Martín 
dc.contributor.authorCheuquepan Valenzuela, William 
dc.contributor.authorHuidobro Lago, María 
dc.contributor.authorCuevas Vicario, José Vicente 
dc.contributor.authorHernández Muñoz, Sheila 
dc.contributor.authorHeras Vidaurre, Aránzazu 
dc.contributor.authorColina Santamaría, Álvaro 
dc.coverage.temporalstart=2022; end=2022es
dc.date.accessioned2023-05-29T10:08:54Z
dc.date.available2023-05-29T10:08:54Z
dc.date.issued2023-05-29
dc.identifier.citationPérez Estébanez, Martín; Cheuquepan Valenzuela, William; Huidobro Lago, María; Cuevas Vicario, José Vicente; Hernández Muñoz, Sheila; Heras Vidaurre, Aránzazu; Colina Santamaría, Álvaro; 2023; Dataset of the work “Raman spectroelectrochemical determination of clopyralid in tap water”; RIUBU; http://doi.org/10.36443/10259/7684en
dc.identifier.urihttp://hdl.handle.net/10259/7684
dc.description.abstractClopyralid is a common herbicide used all around the world that can be dissolved in the rain stream and accumulate in underground water with the potential threat of reaching drinking water. Many methodologies have been proposed to perform quantitative analysis of this compound but, to this day, no Raman detection of clopyralid has been carried out. Here, a novel methodology to quantify clopyralid, based on Electrochemical Surface Oxidation-Enhanced Raman Scattering (EC-SOERS), is developed, using disposable silver screen-printed electrodes as substrate. The optimization of the electrolytic media is carried out, searching for the conditions where a maximum Raman enhancement is obtained. Moreover, a study about the effect of various interfering compounds, which could be present in water, on the clopyralid Raman response is performed. The results demonstrate that the presented methodology allows the determination of clopyralid in the micromolar range in tap water without any purification or preconcentration step, requiring few minutes to perform the measurement of each sample.es
dc.description.sponsorshipAuthors acknowledge Ministerio de Ciencia e Innovacion and Agencia Estatal de Investigacion (MCIN/AEI/10.13039/501100011033, PID2020-113154RB-C21), Junta de Castilla y Leon (Grant BU297P18) and Ministerio de Ciencia, Innovacion y Universidades (RED2018–102412-T) for the support of this work. Martín Perez and Sheila Hernandez acknowledge Junta de Castilla y Leon for their predoctoral contracts.es
dc.format.mimetypetext/plain
dc.format.mimetypetext/csv
dc.format.mimetypetext/x-log
dc.format.mimetypeapplication/zip
dc.language.isoenges
dc.publisherUniversidad de Burgoses
dc.relation.isreferencedbyhttp://hdl.handle.net/10259/7434
dc.rightsAtribución 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectSpectroelectrochemistryes
dc.subjectEC-SOERSes
dc.subjectSERSes
dc.subjectRamanes
dc.subjectHerbicideses
dc.subject.otherQuímica analíticaes
dc.subject.otherChemistry, Analytices
dc.titleDataset of the work “Raman spectroelectrochemical determination of clopyralid in tap water”es
dc.typedatasetes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.identifier.doi10.36443/10259/7684
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-113154RB-C21/ES/APLICACION DE NUEVOS MATERIALES Y DISPOSITIVOS PARA EC-SERS Y EC-SOERS/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Castilla y León//BU297P18//Fusión de técnicas espectroelectroquímicas avanzadas/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RED2018-102412-T/ES/RED DE SENSORES Y BIOSENSORES ELECTROQUIMICOS/es
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones
dc.publication.year2023


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