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dc.contributor.authorHernández Muñoz, Sheila 
dc.contributor.authorPerales Rondon, Juan Víctor 
dc.contributor.authorHeras Vidaurre, Aránzazu 
dc.contributor.authorColina Santamaría, Álvaro 
dc.coverage.temporalstart=2020; end=2022es
dc.date.accessioned2023-05-29T10:42:29Z
dc.date.available2023-05-29T10:42:29Z
dc.date.issued2023-05-29
dc.identifier.citationHernández Muñoz, Sheila; Perales Rondon, Juan Víctor; Heras Vidaurre, Aránzazu; Colina Santamaría, Álvaro; 2023; Dataset of the work “Simultaneous Raman and reflection UV/Vis absorption spectroelectrochemistry”; RIUBU; http://doi.org/10.36443/10259/7685en
dc.identifier.urihttp://hdl.handle.net/10259/7685
dc.description.abstractIn the present work, a new combination of Raman and ultraviolet and visible (UV/Vis) absorption spectroelectrochemistry in reflection mode is proposed. The new experimental setup allows obtaining the two kinds of spectroscopic data without interferences concomitantly with the electrochemical information. To the best of our knowledge, it is the first time to report the simultaneous obtention of electrochemical, electronic, and vibrational information in the same experiment. This new combination provides time-resolved information about the processes that are taking place on the electrode/solution interface which has significant implications in different fields of chemistry, such as modification of electrodes, studies of electrocatalytic reaction mechanisms, development of sensors, among others. Two different systems were used to demonstrate the advantages and capabilities of the brand-new technique, namely, the oxidation of potassium ferrocyanide, an out-sphere system that is usually employed in the validation of SEC techniques, and the electrochemical-surface enhanced Raman spectroscopy (EC-SERS) detection of crystal violet by in-situ formation of the silver SERS substrate, where the UV/Vis spectra were used to follow the formation of the SERS substrate, whereas the Raman response of a probe molecule was used to confirm either the formation of a nanostructured surface and to obtain the fingerprint of the molecule with a high time resolution. The brand-new experimental setup has shown to be useful, versatile, robust, compact, and easy to use for future applications.es
dc.description.sponsorshipAuthors acknowledge the financial support from Ministerio de Ciencia e Innovacion (No. PID2020-113154RB-C21), Ministerio de Economía, Industria y Competitividad (No. CTQ2017-83935-RAEI/FEDERUE), Junta de Castilla y Leon (No. BU297P18), and Ministerio de Ciencia, Innovacion y Universidades (No. RED2018-102412-T). J.V.P-R acknowledges Spanish Ministry of Economy, Industry, and Competitiveness for the Juan de la Cierva postdoctoral (No. FJCI-2017-32458) and the University of Alcala (No. CCG19/CC-071). S.H. thanks JCyL and European Social Fund for her predoctoral fellowship.es
dc.format.mimetypetext/plain
dc.format.mimetypetext/csv
dc.language.isoenges
dc.publisherUniversidad de Burgoses
dc.rightsAtribución 4.0 Internacional*
dc.rightsAtribución 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectSpectroelectrochemistryes
dc.subjectSurface enhanced Raman spectroscopy (SERS)es
dc.subjectRamanes
dc.subjectUltraviolet and visible (UV/Vis)es
dc.subjectAbsorptiones
dc.subjectNanoparticleses
dc.subject.otherQuímica analítica
dc.subject.otherChemistry, Analytic
dc.titleDataset of the work “Simultaneous Raman and reflection UV/Vis absorption spectroelectrochemistry”es
dc.typedatasetes
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.identifier.doi10.36443/10259/7685
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-113154RB-C21/ES/APLICACION DE NUEVOS MATERIALES Y DISPOSITIVOS PARA EC-SERS Y EC-SOERS/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-83935-R/ES/ESPECTROELECTROQUIMICA RAMAN CUANTITATIVA/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Castilla y León//BU297P18//Fusión de técnicas espectroelectroquímicas avanzadas/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RED2018-102412-T/ES/RED DE SENSORES Y BIOSENSORES ELECTROQUIMICOS/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/FJCI-2017-32458/ES/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/UAH//CCG19%2FCC-071/es
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones
dc.publication.year2023


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