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dc.contributor.authorParra de la Parra, Sandra de la 
dc.contributor.authorTamayo Ramos, Juan Antonio 
dc.contributor.authorRubio Presa, Rubén 
dc.contributor.authorPerez Antolin, Daniel 
dc.contributor.authorRuiz Fernández, Virginia 
dc.contributor.authorSanz Díez, Roberto 
dc.contributor.authorRumbo Lorenzo, Carlos 
dc.contributor.authorVentosa Arbaizar, Edgar 
dc.date.accessioned2023-09-18T10:08:42Z
dc.date.available2023-09-18T10:08:42Z
dc.date.issued2023-09
dc.identifier.issn1864-5631
dc.identifier.urihttp://hdl.handle.net/10259/7813
dc.description.abstractViologen-derivatives are the most widely used redox organic molecules for neutral pH negative electrolyte of redox flow batteries. However, the long-established toxicity of the herbicide methyl-viologen raises concern for deployment of viologen-derivatives at large scale in flow batteries. Herein, we demonstrate the radically different cytotoxicity and toxicology of a series of viologen-derivatives in in vitro assays using model organisms representative of human and environmental exposure, namely human lung carcinoma epithelial cell line (A549) and the yeast Saccharomyces cerevisiae. The results show that safe viologen derivatives can be molecularly engineered, representing a promising family of negolyte materials for neutral redox flow batteries.en
dc.description.sponsorshipThe authors acknowledge financial support by the Spanish Government (Ministerio de Ciencia e Innovacion, Grants PID2021-124974OB-C22 and PID2020-115789GB-C21) and Ramon y Cajal award (RYC2018-026086-I) as well as the MeBattery project. MeBattery has received funding from the European Innovation Council of the European Union under Grant Agreement no. 101046742. This work was supported by the Regional Government of Castilla y Leon (Junta de Castilla y Leon) and by the Ministry of Science and Innovation MICIN and the European Union NextGenerationEU/PRTR. We also gratefully acknowledge Junta de Castilla y Leon (BU049P20) and FEDER for financial support.en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherWiley-VCHes
dc.relation.ispartofChemSusChem. 2023, e202300626es
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectCytotoxicityen
dc.subjectToxicologyen
dc.subjectViologen derivativesen
dc.subjectAnolyteen
dc.subjectRedox flow batteryen
dc.subject.otherQuímica analíticaes
dc.subject.otherChemistry, Analyticen
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.titleOn the Tunability of Toxicity for Viologen‐Derivatives as Anolyte for Neutral Aqueous Organic Redox Flow Batteriesen
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.1002/cssc.202300626es
dc.identifier.doi10.1002/cssc.202300626
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-124974OB-C22/ES/Procesos Redox mediados para baterias de flujo/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115789GB-C21/ES/ESTRATEGIAS SINTETICAS SOSTENIBLES PARA LA TRANSFORMACION DIRECTA DE NITROCOMPUESTOS Y DESARROLLO DE NUEVAS REACCIONES CATALIZADAS POR ORO/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RYC2018-026086-I/ES/es
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/HE/101046742/EU/MEDIATED BIPHASIC BATTERY/MeBatteryen
dc.relation.projectIDinfo:eu-repo/grantAgreement/Junta de Castilla y León//BU049P20//Estrategias sintéticas sostenibles para la halogenación directa de nitrocompuestos y la preparación de electrolitos orgánicos para baterías de flujo redox/es
dc.identifier.essn1864-564X
dc.journal.titleChemSusChemes
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones


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