Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/8221
Título
New fluorescent reporters capable of Ultra-sensitively detecting trinitrotoluene on surfaces: A proof-of-concept for finding hidden nitroaromatics in the workroom
Autor
Publicado en
Journal of Photochemistry and Photobiology A: Chemistry. 2023, V. 444, 114911
Editorial
Elsevier
Fecha de publicación
2023-10
ISSN
1010-6030
DOI
10.1016/j.jphotochem.2023.114911
Abstract
We describe the proof of concept of a portable testing setup for the detection of trinitrotoluene (TNT), a common component in hidden explosive devices. The system allows for field-testing and generation of real-time results to test for TNT traces in surfaces by simply using a filter paper and a fluorescent reporter. In this way, the controlled trapping and detection of the analyte by a chemical sensor gives reliable results at extremely low concentrations of TNT on surfaces under real life conditions suitable for daily use in ordinary sampling for example at airlines luggage storage or sport locker rooms. The reported fluorescent methodology is very sensitive and selective, allowing for the trapping and detection of TNT by a fluorescent reporter to give reliable results at very low concentrations. As a complement, we report the preparation of a modified Sylgard film that is useful under real conditions for qualitative fluorescent detection of hidden traces of TNT on surfaces or fingers by a swab method. The combination of quantitative and qualitative detection of TNT traces on surfaces constitutes a comprehensive new method for the detection of hidden nitroaromatic explosives in the workplace.
Palabras clave
2,4,6-Trinitrotoluene
Improvised explosive devices
Chemical sensors
Fluorescent materials
Chemical tests
Swab alternatives
Materia
Química orgánica
Chemistry, Organic
Versión del editor
Collections
Documento(s) sujeto(s) a una licencia Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 Internacional