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dc.contributor.authorNavarro Cuñado, A. Marta 
dc.contributor.authorGarcía Ruiz, Begoña 
dc.contributor.authorHoyuelos Álvaro, Fco. Javier 
dc.contributor.authorPeñacoba Maestre, Indalecio A. 
dc.contributor.authorIbeas Cortes, Saturnino 
dc.contributor.authorLeal Villalba, José María 
dc.date.accessioned2023-12-20T11:28:41Z
dc.date.available2023-12-20T11:28:41Z
dc.date.issued2012-08
dc.identifier.issn1520-6106
dc.identifier.urihttp://hdl.handle.net/10259/8227
dc.description.abstractHeat capacities for the binary mixtures of methanol with (C1–C4) alkylbenzoates and methylbenzoate with (C1–C11) alkan-1-ols have been measured over the whole composition range at 298.15 K under atmospheric pressure. From the experimental measurements, the derived excess molar heat capacities and partial excess molar heat capacities at infinite dilution have been calculated. A Redlich–Kister-type equation was fitted to these data, and the fitting parameters and standard deviations have been evaluated. Likewise, the IR spectra for the same systems have been recorded as a function of composition. The sets of experimental data gathered contribute to shed light onto the solvent structure and the underlying molecular interactions between the mixture constituents. The conclusions drawn have been established in terms of solute–solvent and solvent–solvent interactions and the ensuing structural effects between the solvent constituents.en
dc.description.sponsorshipThe financial support by Junta de Castilla y León, Project GR257, Ministerio de Educación y Ciencia, Project CTQ2009-13051/BQU, supported by FEDER, and Universidad de Burgos with funding by Caja de Burgos, Spain is gratefully acknowledged.en
dc.format.mimetypeapplication/vnd.ms-word
dc.language.isoenges
dc.publisherAmerican Chemical Societyen
dc.relation.ispartofThe Journal of Physical Chemistry B. 2012, V. 116, n. 32, p. 9768–9775en
dc.subjectAlcoholsen
dc.subjectHeat capacityen
dc.subjectMixturesen
dc.subjectOrganic compoundsen
dc.subjectSolventsen
dc.subject.otherQuímica físicaes
dc.subject.otherChemistry, Physical and theoreticalen
dc.titleHeat Capacity Behavior and Structure of Alkan-1-ol/Alkylbenzoate Binary Solventsen
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.1021/jp302934bes
dc.identifier.doi10.1021/jp302934b
dc.identifier.essn1520-5207
dc.journal.titleThe Journal of Physical Chemistry Ben
dc.volume.number116es
dc.issue.number32es
dc.page.initial9768es
dc.page.final9775es
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones


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