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dc.contributor.authorNavarro Cuñado, A. Marta 
dc.contributor.authorGarcía Ruiz, Begoña 
dc.contributor.authorIbeas Cortes, Saturnino 
dc.contributor.authorHoyuelos Álvaro, Fco. Javier 
dc.contributor.authorPeñacoba Maestre, Indalecio A. 
dc.contributor.authorLeal Villalba, José María 
dc.date.accessioned2023-12-20T11:50:33Z
dc.date.available2023-12-20T11:50:33Z
dc.date.issued2013-10
dc.identifier.issn1520-6106
dc.identifier.urihttp://hdl.handle.net/10259/8228
dc.description.abstractThe structure and dynamics of alkan-1-ol/alkylbenzoate binary mixtures have been studied by microwave dielectric relaxation spectroscopy in the 200 MHz to 20 GHz frequency range. The binary mixtures of methanol, ethanol, propan-1-ol, butan-1-ol, and pentan-1-ol with methyl, ethyl, propyl, and butyl benzoates were studied at 298.15 K. The relaxational response of the pure alcohols, pure esters, and their binary mixtures over the full composition range is properly described by the Havriliak–Negami model. The alcohol content, alcohol length, and alkyl side-chain effects on the relaxational properties have been studied for these mixtures over the whole composition range. From the experimental readings, the effective and the corrective Kirkwood and Bruggeman correlation factors have been calculated. The data gathered have been interpreted in terms of the alkyl side-chain effect and their reliance on the mixture composition.en
dc.description.sponsorshipThe financial support by Junta de Castilla y León, Fondo Social Europeo, Project BU-299A12-1 is gratefully acknowledged.en
dc.format.mimetypeapplication/vnd.ms-word
dc.language.isoenges
dc.publisherAmerican Chemical Societyen
dc.relation.ispartofThe Journal of Physical Chemistry B. 2013, V. 117, n. 39, p. 11765–11771en
dc.subjectAlcoholsen
dc.subjectEthanolen
dc.subjectMixturesen
dc.subjectOrganic compoundsen
dc.subjectSolventsen
dc.subject.otherQuímica físicaes
dc.subject.otherChemistry, Physical and theoreticalen
dc.titleMicrowave Dielectric Relaxation Spectroscopy Study of Alkan-1-ol/Alkylbenzoate Binary Solventsen
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.1021/jp406609res
dc.identifier.doi10.1021/jp406609r
dc.identifier.essn1520-5207
dc.journal.titleThe Journal of Physical Chemistry Ben
dc.volume.number117es
dc.issue.number39es
dc.page.initial11765es
dc.page.final11771es
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones


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