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dc.contributor.authorNavarro Cuñado, A. Marta 
dc.contributor.authorGarcía Ruiz, Begoña 
dc.contributor.authorHoyuelos Álvaro, Fco. Javier 
dc.contributor.authorPeñacoba Maestre, Indalecio A. 
dc.contributor.authorLeal Villalba, José María 
dc.date.accessioned2023-12-20T12:46:58Z
dc.date.available2023-12-20T12:46:58Z
dc.date.issued2016-12
dc.identifier.issn0378-3812
dc.identifier.urihttp://hdl.handle.net/10259/8230
dc.description.abstractThis work deals with the structure and solvation ability of the binary mixtures of the essential oil 1,8-cineole with n-hexane, n-octane and n-decane. The relevant derived properties excess isobaric heat capacity, molar excess volume, mixing viscosity, excess isentropic compressibility and activation Gibbs free energy were calculated from the measurements of the respective thermophysical properties carried out at atmospheric pressure in a wide range of temperatures. The data obtained were correlated with the solvent composition over the whole range and interpreted in terms of structural features and molecular interactions. The observed effect of temperature and the underlying interactions stress the propensity of the pure hydrocarbons for packing and folding. The solvation ability of the mixed solvents was assessed with the preferential solvation model, using the solvatochromic probes 2-nitroanisole and 4-nitroaniline, and the Hansen solubility parameters as well, the mixtures displaying stronger solvation power than the pure constituents.en
dc.description.sponsorshipThe financial support of the projects OSLC-2012-007 Obra Social “la Caixa” and CTQ 2014-58812-C2-2-R MINECO, Spain, is gratefully acknowledged.en
dc.format.mimetypeapplication/vnd.ms-word
dc.language.isoenges
dc.publisherElsevieres
dc.relation.ispartofFluid Phase Equilibria. 2016, V. 429, p. 127-136en
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectEssential oilsen
dc.subject1,8-Cineoleen
dc.subjectHydrocarbonen
dc.subjectExcess propertiesen
dc.subjectPreferential solvationen
dc.subject.otherQuímica físicaes
dc.subject.otherChemistry, Physical and theoreticalen
dc.titlePreferential solvation and mixing behaviour of the essential oil 1,8-cineole with short–chain hydrocarbonsen
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.1016/j.fluid.2016.08.035es
dc.identifier.doi10.1016/j.fluid.2016.08.035
dc.journal.titleFluid Phase Equilibriaen
dc.volume.number429es
dc.page.initial127es
dc.page.final136es
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones


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