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dc.contributor.authorPertejo Fernández, Pablo
dc.contributor.authorSancho Medina, Andrea
dc.contributor.authorHermosilla, Tomás
dc.contributor.authorGonzález Saiz, Beatriz 
dc.contributor.authorGómez Ayuso, Javier 
dc.contributor.authorQuesada Pato, Roberto 
dc.contributor.authorMoreno Mediavilla, Daniel 
dc.contributor.authorCarreira Barral, Israel 
dc.contributor.authorGarcía Valverde, María 
dc.date.accessioned2024-02-07T09:07:18Z
dc.date.available2024-02-07T09:07:18Z
dc.date.issued2021-02
dc.identifier.urihttp://hdl.handle.net/10259/8613
dc.description.abstractThe use of arylglyoxal as starting material in Passerini and Ugi reactions affords βketoamides. This has allowed to study keto-enol tautomerism in these systems and assess the way in which the presence of acyloxy or aminoacyl groups bound to the C2 position affects such tautomerism, and to investigate the reactivity of both the enol and carbonyl forms. In this work we also prove the versatility of the Passerini reaction, since depending on the conditions to which the corresponding adducts are subjected different products of synthetic interest can be obtained.en
dc.description.sponsorshipThis research was funded by Consejería de Educación de la Junta de Castilla y León, project BU075G19.en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherMDPIen
dc.relation.ispartofMolecules. 2021, V. 26, n. 4, 919en
dc.rightsAtribución 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectKeto-enol tautomerismen
dc.subjectPasserini adducten
dc.subjectUgi adducten
dc.subjectLactoneen
dc.subjectLactameen
dc.subject2-hydroxyglutaric aciden
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.titleKeto-Enol Tautomerism in Passerini and Ugi Adductsen
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.3390/molecules26040919es
dc.identifier.doi10.3390/molecules26040919
dc.identifier.essn1420-3049
dc.journal.titleMoleculesen
dc.volume.number26es
dc.issue.number4es
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones


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