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dc.contributor.authorHernández Ruiz, Raquel 
dc.contributor.authorGómez Gil, Sara 
dc.contributor.authorPedrosa Sáez, María de los Remedios 
dc.contributor.authorSuárez Pantiga, Samuel 
dc.contributor.authorSanz Díez, Roberto 
dc.date.accessioned2024-07-01T06:55:37Z
dc.date.available2024-07-01T06:55:37Z
dc.date.issued2023-09-08
dc.identifier.issn1477-0520
dc.identifier.urihttp://hdl.handle.net/10259/9325
dc.description.abstractHerein, we report the direct synthesis of a wide variety of functionalized aromatic bromides, chlorides, iodides, and fluorides from nitroarenes in a sequential one-pot operation. This protocol is based on an air- and moisture-tolerant dioxomolybdenum-catalyzed reduction of nitroaromatics, employing pinacol as a reducing agent, which enables subsequent diazotization and halogenation steps. This methodology represents a step-economical, practical, and alternative procedure for synthesizing haloaromatics directly from nitroaromatics.en
dc.description.sponsorshipWe gratefully acknowledge the Ministerio de Ciencia e Innovación MCIN/AEI/10.13039/501100011033 (PID2020-115789GB-C21) and the Junta de Castilla y León and FEDER (BU049P20) for financial support. R. H.-R. and S. G.-G. thank the Ministerio de Educación for FPU predoctoral contracts. S. S.-P. thanks the Ministerio de Ciencia e Innovación and the “NextGenerationEU”/PRTR EU for a Ramón y Cajal contract (RYC2021-031533-I).en
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherRoyal Society of Chemistryen
dc.relation.ispartofOrganic & Biomolecular Chemistry. 2023, V. 21, n. 38, p. 7791-7798en
dc.rightsAtribución-NoComercial 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.subject.otherBiología moleculares
dc.subject.otherMolecular biologyen
dc.titleDirect synthesis of haloaromatics from nitroarenes via a sequential one-pot Mo-catalyzed reduction/Sandmeyer reactionen
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttps://doi.org/10.1039/D3OB01187Aes
dc.identifier.doi10.1039/D3OB01187A
dc.identifier.essn1477-0539
dc.journal.titleOrganic & Biomolecular Chemistryen
dc.volume.number21es
dc.issue.number38es
dc.page.initial7791es
dc.page.final7798es
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones


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