RT info:eu-repo/semantics/article
T1 Luminescent complexes of iridium(iii) with aliphatic amines and detection of biogenic amines
A1 Cuevas Vicario, José Vicente
A1 García Calvo, Víctor
A1 García Calvo, José
A1 Fernández Espinosa, Iván
A1 Carbayo Martín, Mª Aránzazu
A1 Rojo Cámara, Mª Josefa
A1 Rodríguez Rodríguez, Mª Teresa
A1 García Herbosa, Gabriel
A1 Torroba Pérez, Tomás
K1 Biogenic amines
K1 Iridium
K1 Platinum group complexes
K1 Quantum chemistry
K1 Sensors
K1 Química inorgánica
K1 Chemistry, Inorganic
AB The straightforward reaction of [Ir2(ppy)4(µ-Cl)2] with an excess of aliphatic amines yields luminescent iridium complexes of general formula [IrCl(ppy)2(amine)] [amine = n-octylamine (1), t-butylamine (2), piperidine (3)]. The higher sterical hindrance of the amine in complex 2 was the responsible of its equilibrium with the starting materials. The luminescence of 1 and 3 has been studied showing emission at 508 and 509 nm respectively. As the aliphatic amines can be considered models of biogenic amines, this luminescence has been used to explore the viability of this reaction in the detection of biogenic amines. The exposition to vapors of biogenic amines of a solution of [Ir2(ppy)4(µ-Cl)2] in CH2Cl2 or in different solid supports, showed that it was possible to detect the amines in a quick and easy way, with limits of detection value (in solution of methylene chloride) of 4.8 µM for cadaverine.
PB Elsevier
SN 0020-1693
YR 2020
FD 2020-05
LK http://hdl.handle.net/10259/5237
UL http://hdl.handle.net/10259/5237
LA eng
NO Ministerio de Economía y Competitividad, Spain (Project CTQ2015-71353-R), Junta de Castilla y León, Consejería de Educación y Cultura y Fondo Social Europeo (Project BU263P18) and Junta de Castilla y León, Consejería de Educación (Project BU087G19)
DS Repositorio Institucional de la Universidad de Burgos
RD 28-abr-2024