RT info:eu-repo/semantics/article
T1 Mo–Catalyzed One-Pot Synthesis of N-Polyheterocycles from Nitroarenes and Glycols with Recycling of the Waste Reduction Byproduct. Substituent-Tuned Photophysical Properties
A1 Hernández Ruiz, Raquel
A1 Rubio Presa, Rubén
A1 Suarez Pantiga, Samuel
A1 Pedrosa Sáez, María de los Remedios
A1 Fernández Rodríguez, Manuel A.
A1 Tapia Estévez, M" José
A1 Sanz Díez, Roberto
K1 Dioxomolybdenum
K1 N-heterocycles
K1 Nitroaromatics
K1 Photophysical properties
K1 Reuse of waste
K1 Química orgánica
K1 Chemistry, Organic
AB A catalytic domino reduction–imine formation–intramolecular cyclization–oxidation for the general synthesisof a wide variety of biologically relevant N-polyheterocycles,such as quinoxaline- and quinoline-fused derivatives, andphenanthridines, is reported. A simple, easily available, andenvironmentally friendly dioxomolybdenum(VI) complex hasproven to be a highly efficient and versatile catalyst fortransforming a broad range of starting nitroarenes involvingseveral redox processes. Not only is this a sustainable, stepeconomicalas well as air- and moisture-tolerant method, butalso it is worth highlighting that the waste byproductgenerated in the first step of the sequence is recycled andincorporated in the final target molecule, improving theoverall synthetic efficiency. Moreover, selected indoloquinoxalineshave been photophysically characterized incyclohexane and toluene with exceptional fluorescencequantum yields above 0.7 for the alkyl derivatives.
PB Wiley
SN 1521-3765
YR 2021
FD 2021-09
LK http://hdl.handle.net/10259/6091
UL http://hdl.handle.net/10259/6091
LA eng
NO Junta de Castilla y León andFEDER (BU291P18 and BU049P20) and Ministerio de Economía yCompetitividad (MINECO) and FEDER (CTQ2016-75023-C2-1P)for financial support. The project leading to these results hasalso received funding from “la Caixa” Foundation, under theagreement (LCF/PR/PR18/51130007) (CAIXA-UBU001). R.H.-R.thanks Ministerio de Educación for a FPU predoctoral contract.S.S􀀀 P. thanks Junta de Castilla y León and FSE and FEDER for apostdoctoral contract.
DS Repositorio Institucional de la Universidad de Burgos
RD 27-abr-2024