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    Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/4288

    Título
    Synthesis of α-functionalized α-indol-3-yl carbonyls through direct SN reactions of indol-3-yl α-acyloins
    Autor
    Suárez, AnisleyUBU authority
    Martínez Lara, FernandoUBU authority Orcid
    Sanz Díez, RobertoUBU authority Orcid
    Publicado en
    Organic & Biomolecular Chemistry. 2016, V. 14, n. 47, p. 11212-11219
    Editorial
    Royal Society of Chemistry
    Fecha de publicación
    2016-12
    ISSN
    1477-0520
    DOI
    10.1039/c6ob02125e
    Abstract
    A new and efficient synthesis of α-functionalized α-indol-3-yl ketones from easily available indolyl α-acyloins is reported. This process, catalyzed by Brønsted or Lewis acids, involves an uncommon direct nucleophilic substitution reaction of a secondary α-carbonyl-substituted hydroxyl group. The described methodology allows the introduction of a variety of nucleophiles such as (hetero)arenes, thiophenols, nitroanilines and 1,3-dicarbonyl derivatives. The synthesized α-indol-3-yl carbonyl compounds are important synthetic targets also useful for accessing functionalized tryptophols and furan-3-yl indoles.
    Materia
    Química orgánica
    Chemistry, Organic
    URI
    http://hdl.handle.net/10259/4288
    Versión del editor
    http://dx.doi.org/10.1039/c6ob02125e
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    • Artículos SINTORG
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