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    Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/5342

    Título
    Thermodynamics of binary mixtures 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane (HFE-7200) + 2-propanol: High pressure density, speed of sound and derivative properties
    Autor
    Muñoz Rujas, NataliaAutoridad UBU Orcid
    Aguilar Romero, FernandoAutoridad UBU Orcid
    García Alonso, Jesús MarcosAutoridad UBU Orcid
    Montero García, EduardoAutoridad UBU Orcid
    Publicado en
    The Journal of Chemical Thermodynamics. 2019, V. 131, p. 630-647
    Editorial
    Elsevier
    Fecha de publicación
    2019-04
    ISSN
    0021-9614
    DOI
    10.1016/j.jct.2018.12.018
    Résumé
    Awareness about environmental impact of greenhouse gas emissions has lead to search for other alternatives which can cover the same utility range of wellknown CFCs, HCFCs and PFCs but without their undesirable effects on the planet. Since Hydrofluoroether fluids (HFEs) have emerged as a good alternative, it is necessary to characterize their thermophysical properties in order to bring reliable data to the industry. Density and speed of sound are two of the most important physical properties because of the amount of information that they provide in the design of the machinery involved in the utilization of these fluids as well as data for the parametrization of equations of state. This paper reports a set of new data concerning high pressure density, ρ, for the binary mixture x HFE-7200 + (1 − x) 2-propanol in a broad range of pressures (0.1–140 MPa), and at several temperatures (from 293.15 to 393.15 K). Density values were correlated by employing a Tait-like equation in the same p, T ranges, and the derivative properties, that is, the isothermal compressibility κT, and the isobaric expansion αP, were determined. Excess molar volumes VE, which bring information about the change in volume observed in the mixture were also calculated for the eight mole fractions investigated. Speeds of sound, c, at 0.1 MPa were measured experimentally in the temperature range (293.15–333.15 K). By using the Laplace equation, isentropic compressibilities, κS, were calculated from density and sound velocity values.
    Palabras clave
    1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane
    2-propanol
    Density
    Derivative properties
    Excess volumes
    Materia
    Química
    Chemistry
    Termodinámica
    Thermodynamics
    URI
    http://hdl.handle.net/10259/5342
    Versión del editor
    https://doi.org/10.1016/j.jct.2018.12.018
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    muñoz-tjct_2019.pdf
    Tamaño:
    1.290Mo
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