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    Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/4762

    Título
    Tetrahydroborates: development and potential as hydrogen storage medium
    Autor
    Puszkiel, Julián .
    Garroni, SebastianoAutoridad UBU Orcid
    Milanese, Chiara .
    Gennari, Fabiana C.
    Klassen, Thomas .
    Dornheim, Martin .
    Pistidda, Claudio .
    Publicado en
    Inorganics. 2017, V. 5, n. 4, 74
    Editorial
    MDPI
    Fecha de publicación
    2017-12
    ISSN
    2304-6740
    DOI
    10.3390/inorganics5040074
    Resumen
    The use of fossil fuels as an energy supply becomes increasingly problematic from the point of view of both environmental emissions and energy sustainability. As an alternative, hydrogen is widely regarded as a key element for a potential energy solution. However, different from fossil fuels such as oil, gas, and coal, the production of hydrogen requires energy. Alternative and intermittent renewable sources such as solar power, wind power, etc., present multiple advantages for the production of hydrogen. On one hand, the renewable sources contribute to a remarkable reduction of pollutants released to the air. On the other hand, they significantly enhance the sustainability of energy supply. In addition, the storage of energy in form of hydrogen has a huge potential to balance an effective and synergetic utilization of the renewable energy sources. In this regard, hydrogen storage technology presents a key roadblock towards the practical application of hydrogen as “energy carrier”. Among the methods available to store hydrogen, solid-state storage is the most attractive alternative both from the safety and the volumetric energy density points of view. Because of their appealing hydrogen content, complex hydrides and complex hydride-based systems have attracted considerable attention as potential energy vectors for mobile and stationary applications. In this review, the progresses made over the last century on the development in the synthesis and research on the decomposition reactions of homoleptic tetrahydroborates is summarized. Furthermore, theoretical and experimental investigations on the thermodynamic and kinetic tuning of tetrahydroborates for hydrogen storage purposes are herein reviewed.
    Palabras clave
    Tetrahydroborates
    Synthesis
    Decomposition pathways
    Tailoring
    Solid state hydrogen storage
    Materia
    Materia-Composición
    Matter-Constitution
    Química inorgánica
    Chemistry, Inorganic
    URI
    http://hdl.handle.net/10259/4762
    Versión del editor
    https://doi.org/10.3390/inorganics5040074
    Aparece en las colecciones
    • Artículos ICCRAM
    Attribution 4.0 International
    Documento(s) sujeto(s) a una licencia Creative Commons Attribution 4.0 International
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    Nombre:
    Puszkiel-Inorganics_2017.pdf
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    335.2Kb
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