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    Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/4272

    Título
    Activity coefficients at infinite dilution of volatile compounds in water: effect of temperature and salt concentration
    Autor
    Martínez Velasco, RodrigoAutoridad UBU
    Sanz Díez, Mª TeresaAutoridad UBU Orcid
    Beltrán Calvo, SagrarioAutoridad UBU Orcid
    Corcuera Tecedor, ElenaAutoridad UBU
    Publicado en
    Journal of Chemical and Engineering Data. 2012, V. 57, n. 5, p 1480–1485
    Editorial
    American Chemical Society
    Fecha de publicación
    2012-05
    ISSN
    0021-9568
    DOI
    10.1021/je2013878
    Abstract
    Activity coefficients at infinite dilution in water have been determined for some aroma compounds detected in brown crab liquid effluent produced during boiling (1-octen-3-ol, 1-penten-3-ol, 3-methylbutanal, hexanal, benzaldehyde, 2,3-pentadione, and ethyl acetate) by using the headspace gas chromatography technique (HSGC). Experimental data have been obtained over the temperature range of (40 to 50) °C. In this work, activity coefficients at infinite dilution for different kinds of systems have been considered: one component solute + water and multicomponent solute + water. No significant differences were observed between activity coefficients obtained in these two kinds of systems. Additionally the effect of salt concentration at 40 °C has been studied by varying the salt concentration from (0 to 1.71) mol·kg−1. Experimental data were fitted as a function of salt concentration by using the Setschenow equation, obtaining the salting-out coefficient.
    Palabras clave
    aroma compounds
    activity coefficients at infinite dilution
    salt effect
    temperature effect
    Materia
    Ingeniería química
    Chemical engineering
    URI
    http://hdl.handle.net/10259/4272
    Versión del editor
    http://dx.doi.org/10.1021/je2013878
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