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    Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/4771

    Título
    Study of the effect of the presence of silver nanoparticles on migration of bisphenol A from polycarbonate glasses into food simulants
    Autor
    Reguera Alonso, CeliaUBU authority Orcid
    Sanllorente Méndez, SilviaUBU authority Orcid
    Herrero Gutiérrez, AnaUBU authority Orcid
    Sarabia Peinador, Luis AntonioUBU authority Orcid
    Ortiz Fernández, Mª CruzUBU authority Orcid
    Publicado en
    Chemometrics and Intelligent Laboratory Systems. 2018, V. 176, p. 66-73
    Editorial
    Elsevier
    Fecha de publicación
    2018-05
    ISSN
    0169-7439
    DOI
    10.1016/j.chemolab.2018.03.005
    Abstract
    The impact that the presence of nanoparticles in food can have on the migration from food contact materials (FCMs) of substances, which occurrence in foodstuffs is regulated, is posed in this paper through a case-study. Migration of bisphenol A (BPA) from polycarbonate glasses into aqueous food simulant B (3% acetic acid, w/v) and simulant D1 (50% ethanol, v/v), both in the absence and presence of silver nanoparticles is tested. The analysis of the amount of BPA released into the food simulants is conducted by comparing population results instead of using the classical location and scatter estimates. β-content tolerance intervals are used to model the statistical distribution of BPA migrated from the polycarbonate glasses. Experimental measurements are performed by HPLC-FLD, and partial least squares regression models are then fitted to determine the concentration of BPA. The analytical procedure fulfils the trueness property. The capability of detection of the method is between 1.7 and 2.3 μg L−1 when the probabilities of false positive and false negative are fixed at 0.05. Using β-content tolerance intervals, in 90% of the specimens of a population of polycarbonate glasses, the amount of BPA migrated into simulant B in the presence of AgNPs is 13.34 μg L−1, at least twice the quantity that migrated in the absence of them.
    Palabras clave
    PLS
    HPLC-FLD
    Bisphenol A
    Migration test
    Food simulants
    Silver nanoparticles
    Materia
    Chemistry
    Mathematics
    Química
    Matemáticas
    URI
    http://hdl.handle.net/10259/4771
    Versión del editor
    https://doi.org/10.1016/j.chemolab.2018.03.005
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    Documento(s) sujeto(s) a una licencia Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
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    Reguera-CILS_2018.pdf
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