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    Por favor, use este identificador para citar o enlazar este ítem: https://hdl.handle.net/10259/11380

    Título
    Excess enthalpy, density, speed of sound and refractive index of binary mixtures {2-(2-ethoxyethoxy)ethanol + 1-hexene, or cyclohexane, or methylcyclohexane at (298.15 and 313.15) K: Application of the PPR-78 cubic equation of state, NRTL and UNIQUAC models
    Autor
    Lifi, Mohamed
    Lorenzo, Jorge
    Aguilar Romero, FernandoAutoridad UBU Orcid
    Muñoz Rujas, NataliaAutoridad UBU Orcid
    Montero García, EduardoAutoridad UBU Orcid
    Chhiti, Younes
    Alaoui, Fatima E. M.Autoridad UBU Orcid
    Publicado en
    The Journal of Chemical Thermodynamics. 2021, V. 153, 106306
    Editorial
    Elsevier
    Fecha de publicación
    2021-02
    ISSN
    0021-9614
    DOI
    10.1016/j.jct.2020.106306
    Zusammenfassung
    Excess enthalpy, HE, density, , speed of sound, u, and refractive index, , measured data (312 points) are presented for {2-(2-ethoxyethoxy)ethanol (carbitol) with 1-hexene, or cyclohexane, or methylcyclohexane} at 0.1 MPa and (298.15 and 313.15) K throughout the full range of composition. Consequently, derivative properties were determined from the reported experimental data: , excess volume, , isentropic compressibility, , deviation in isentropic compressibility, , deviation in refractive index. The modified Redlich-Kister is employed for the experimental data correlation of HE, while the Predictive Peng-Robinson 1978 (PPR78) EoS is used to model the measured data of HE. As a comparison with PPR78 EoS, the NRTL and UNIQUAC models are applied to have a prediction on the experimental HE data. Also, the Redlich-Kister equation is employed to fit the excess volume, deviation in isentropic compressibility and deviation in refractive index. In the present work, we have discussed intermolecular interactions for the studied binary mixtures.
    Palabras clave
    Excess enthalpy
    Density
    Speed of sound
    Refractive index
    Oxygenated compound
    Materia
    Termodinámica química
    Thermochemistry
    Mezclas
    Mixtures
    URI
    https://hdl.handle.net/10259/11380
    Versión del editor
    https://doi.org/10.1016/j.jct.2020.106306
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    Lifi-jct_2021.pdf
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