Catalytic Intermolecular Hetero-Dehydro-Diels–Alder Cycloadditions: Regio- and Diasteroselective Synthesis of 5,6-Dihydropyridin-2-ones

Fernandez Garcia, Jesus Manuel; Fernández Rodríguez, Manuel A.; Aguilar, Enrique

doi:10.1021/ol202046y

Por favor, use este identificador para citar o enlazar este ítem: http://hdl.handle.net/10259/3865

Título

Catalytic Intermolecular Hetero-Dehydro-Diels–Alder Cycloadditions: Regio- and Diasteroselective Synthesis of 5,6-Dihydropyridin-2-ones

Autor

Fernandez Garcia, Jesus Manuel

Fernández Rodríguez, Manuel A.

Aguilar, Enrique

Publicado en

Organic letters. 2011, V. 13, n. 19, p. 5172-5175

Editorial

American Chemical Society

Fecha de publicación

2011-10

ISSN

1523-7060

DOI

10.1021/ol202046y

Resumen

A novel catalyzed intermolecular heterodehydro-Diels–Alder reaction between push–pull 1,3-dien-5-ynes and aldimines or silylaldimines is reported. The sequence is promoted both by gold(I) or silver(I) catalysts and leads to the diastereo- and regioselective formation of 5,6-dihydropyridin-2-ones

Materia

Química orgánica

Chemistry, Organic

URI

http://hdl.handle.net/10259/3865

Versión del editor

http://dx.doi.org/10.1021/ol202046y

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