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dc.contributor.authorSanjuán Cortázar, Ana María 
dc.contributor.authorGarcía García, Patricia
dc.contributor.authorFernández Rodríguez, Manuel A. 
dc.contributor.authorSanz Díez, Roberto 
dc.date.accessioned2015-12-10T10:56:51Z
dc.date.available2015-12-10T10:56:51Z
dc.date.issued2013-07
dc.identifier.issn1615-4150
dc.identifier.urihttp://hdl.handle.net/10259/3893
dc.description.abstractAn asymmetric synthesis of elusive chiral cyclopentadienes has been developed by gold(I)-catalyzed alkoxycyclization of 1,3-dien-5-ynes. The application of these substrates in completely diastereoselective Diels–Alder cycloaddition reactions, which can be carried out in one pot from achiral 1,3-dien-5-ynes, allows the preparation of highly functionalized products bearing five stereogenic centers with high enantiomeric excessesen
dc.description.sponsorshipMinisterio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021A09 and GR-172) for financial support. A. M. S. thanks Junta de Castilla y Leon (Consejeria de Educacion) and Fondo Social Europeo for a PIRTU contract. P. G.-G. and M. A. F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contractsen
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherWiley-VCH Verlagen
dc.relation.ispartofAdvanced Synthesis & Catalysis. 2013, V. 355, n. 10, p. 1955–1962en
dc.subjectcycloisomerizationen
dc.subjectcyclopentadienesen
dc.subjectDiels–Alder reactionen
dc.subjectdienynesen
dc.subjectgolden
dc.subject.otherQuímica orgánicaes
dc.titleEnantioselective Synthesis of Cyclopentadienes by Gold(I)- Catalyzed Cyclization of 1,3-Dien-5-ynesen
dc.typeArtículoes
dc.typeinfo:eu-repo/semantics/article
dc.description.versionThis is the peer reviewed version of the following article: Sanjuán, A. M., García-García, P., Fernández-Rodríguez, M. A. and Sanz, R. (2013), Enantioselective Synthesis of Cyclopentadienes by Gold(I)- Catalyzed Cyclization of 1,3-Dien-5-ynes. Adv. Synth. Catal., 355: 1955–1962. doi: 10.1002/adsc.201300448, which has been published in final form at 10.1002/adsc.201300448. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttp://dx.doi.org/10.1002/adsc.201300448
dc.identifier.doi10.1002/adsc.201300448
dc.subject.unescoChemistry, Organicen
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/CTQ2010-15358
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU021A09
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/GR-172
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersionen


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