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dc.contributor.authorGarcía García, Patricia
dc.contributor.authorMartínez Cuezva, Alberto 
dc.contributor.authorSanjuán Cortázar, Ana María 
dc.contributor.authorFernández Rodríguez, Manuel A. 
dc.contributor.authorSanz Díez, Roberto 
dc.date.accessioned2016-01-20T12:31:52Z
dc.date.available2016-01-20T12:31:52Z
dc.date.issued2011-08
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/10259/3908
dc.description.abstractHighly substituted benzene derivatives have been easily prepared in a regioselective way from readily available 1,3-hexadien-5-ynes through a gold(I)-catalyzed tandem reaction. The process involves an initial cyclization followed by a selective Wagner-Meerwein shift in which the migration preference seems to be determined by the ability to stabilize a positive chargeen
dc.description.sponsorshipMinisterio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021A09 and GR-172) for financial suport. A.M. S. thanks Junta de Castilla y Leon for a predoctoral fellowship. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contractsen
dc.description.sponsorshipMinisterio de Ciencia e Innovacion (MICINN) and FEDER (CTQ2010-15358 and CTQ2009-09949/BQU) and Junta de Castilla y Leon (BU021A09 and GR-172) for financial suport. A.M. S. thanks Junta de Castilla y Leon for a predoctoral fellowship. P.G.-G. and M.A.F.-R. thank MICINN for "Juan de la Cierva" and "Ramon y Cajal" contracts
dc.format.mimetypeapplication/pdf
dc.language.isoenges
dc.publisherAmerican Chemical Societyen
dc.relation.ispartofOrganic Letters. 2011, V. 13, n. 18, p. 4970-4973en
dc.subject.otherQuímica orgánicaes
dc.subject.otherChemistry, Organicen
dc.titleGold(I)-Catalyzed Tandem Cyclization–Selective Migration Reaction of 1,3-Dien-5-ynes: Regioselective Synthesis of Highly Substituted Benzenesen
dc.titleinfo:eu-repo/semantics/acceptedVersion
dc.typeArtículoes
dc.typeinfo:eu-repo/semantics/article
dc.description.versionThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic letters, copyright © American Chemical Society after peer review and technical editing by the publisher.
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.relation.publisherversionhttp://dx.doi.org/10.1021/ol202129n
dc.identifier.doi10.1021/ol202129n
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/CTQ2010-15358
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/CTQ2009-09949/BQU
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/BU021A09
dc.relation.projectIDinfo:eu-repo/grantAgreement/JCyL/GR-172


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